Overview on Low-oxidation-state Alkaline Earth Organometallic Chemistry

doi:10.6023/A24100325

Acta Chimica Sinica ›› 2025, Vol. 83 ›› Issue (2): 139-151.DOI: 10.6023/A24100325 Previous Articles Next Articles

Review

低氧化态碱土金属有机化学概述

陈荣, 魏保生^*()

中南大学化学化工学院长沙 410083

投稿日期:2024-10-28 发布日期:2024-12-24

作者简介:

陈荣, 2023年获延安大学学士学位, 同年保送至中南大学化学化工学院攻读硕士学位, 师从魏保生副教授, 目前主要研究主族金属有机化学.

魏保生, 副教授, 博士生导师. 2012年获山东大学学士学位, 2017年获北京大学博士学位(导师: 席振峰院士、张文雄教授), 2018~2021年在德国慕尼黑大学化学系从事博士后研究(合作导师: Paul Knochel教授), 2022年起加入中南大学化学化工学院开展教学科研工作. 主要研究金属有机化学、有机合成与催化化学, 近年来在Acc. Chem. Res.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.等国内外权威期刊发表论文20余篇, 应邀撰写1个英文专著章节, 现担任国际学术期刊Chem. Synth.青年编委, 入选中南大学首批升华学者计划和湖南省高层次人才引进项目.

基金资助:
国家自然科学基金(22271312); 中南大学启动基金和中南大学创新驱动计划项目(2023CXQD047)

Overview on Low-oxidation-state Alkaline Earth Organometallic Chemistry

Rong Chen, Baosheng Wei()

College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China

Received:2024-10-28 Published:2024-12-24
Contact: *E-mail: bswei@csu.edu.cn
Supported by:
National Natural Science Foundation of China(22271312); start-up funds of Central South University and the Central South University Innovation-Driven Research Programme(2023CXQD047)

The chemistry of main group elements with low oxidation states occupies an important position in main group chemistry. Research results in this field can not only enrich the theoretical connotation of chemical bonding, but also have great significance in organometallic chemistry and catalysis, small molecule activation and transformation, etc. Compared with the chemistry of low-oxidation-state p-block elements, the s-block alkaline earth metal elements with low electronegativity can easily lose two valence electrons to form stable ＋2 oxidation state compounds, but it is more difficult to form low-oxidation-state species with relatively low stability and strong reducing property. Therefore, the study on low-oxidation-state alkaline earth organometallic chemistry is full of challenges. This review outlines the development history of low-oxidation-state alkaline earth organometallic chemistry, briefly describes the relatively mature low-oxidation-state magnesium chemistry, comprehensively introduces the low-oxidation-state beryllium chemistry that has recently made significant progress, highlights the low-oxidation-state calcium, strontium, and barium chemistry that still needs urgent breakthrough.

Key words: low oxidation state, alkaline earth metal, organometallic chemistry, beryllium, magnesium, calcium

Cite this article

Rong Chen, Baosheng Wei. Overview on Low-oxidation-state Alkaline Earth Organometallic Chemistry[J]. Acta Chimica Sinica, 2025, 83(2): 139-151.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 32

Figure 1. The first stable and isolable magnesium(I) complex

Figure 2. Synthesis of the dianionic magnesium(I) dimers

Figure 3. Redox potentials of common reductants

Figure 4. Two-electron reduction of organic substrates by magnesium(I) dimers

Figure 5. One-electron reduction of organic substrates by magnesium(I) dimers

Figure 6. Magnesium(I)-catalyzed cyanosilylation of ketones or aldehydes

Figure 7. Synthesis and reactivity of magnesium(I) complex with a new ligand

Figure 8. Synthesis and reactivity of magnesium-azobenzenyl anion radical complex

Figure 9. In situ synthesis and reactivity of magnesium(I) radical compound

Figure 10. Synthesis of magnesium(II)-radical dianion complex

Figure 11. Preparation of unstable magnesium(I) free radical compounds by ball milling

Figure 12. Synthesis and reactivity of the first magnesium(0) complex

Figure 13. Synthesis of the first Mg-N2 complex

Figure 14. Synthesis and reactivity of the first beryllium(0) complex

Figure 15. Synthesis of beryllium(I)-aluminum complexes

Figure 16. Synthesis and reactivity of beryllium radical cation compounds

Figure 17. Synthesis and reactivity of neutral beryllium(I) radical compounds

Figure 18. A reaction via the beryllium(I) radical intermediate

Figure 19. Synthesis and reactivity of diberyllocene

Figure 20. Synthesis and reactivity of heterobimetallic Mg-Be complexes

Figure 21. Synthesis and controversy of inverse sandwich dicalcium(I) complexes

Figure 22. Attempts on the synthesis of calcium(I) complexes supported by bulky BDI* ligands

Figure 23. Synthesis of the first Ca-N2 complex supported by a bulky BDI* ligand

Figure 24. Reactivity of a Ca-N2 complex supported by a bulky BDI* ligand

Figure 25. Synthesis of Ca-N2 complex supported by an extremely bulky diamide ligand

Figure 26. Syntheses of biphenyl-dicalcium complexes

Figure 27. Synthesis and reactivity of azobenzene radical calcium complexes

Figure 28. Synthesis and reactivity of calcium complexes with 2,2'-bipyridyl radical

Figure 29. Synthesis and reactivity of heterobimetallic Mg-Ae complexes

Figure 30. Syntheses of biphenyl-distrontium complexes

Figure 31. The application of Ba(0)/BaH2 in catalytic hydrogenation

Figure 32. Metal vapour synthesis (MVS) of an organometallic Ba(0) synthon

References 47

[1]	Zhao, L.; Pan, S.; Holzmann, N.; Schwerdtfeger, P.; Frenking, G. Chem. Rev. 2019, 119, 8781.
[2]	Jones, C. Nat. Rev. Chem. 2017, 1, 0059.
[3]	Chu, T.; Nikonov, G. I. Chem. Rev. 2018, 118, 3608.
[4]	Melen, R. L. Science 2019, 363, 479.
[5]	(a) Jones, C. Commun. Chem. 2020, 3, 159. pmid: 35756523
	(b) Yadav, S.; Saha, S.; Sen, S. S. ChemCatChem. 2016, 8, 486. pmid: 35756523
	(c) Rösch, B.; Harder, S. Chem. Commun. 2021, 57, 9354. pmid: 35756523
	(d) Freeman, L. A.; Walley, J. E.; Gilliard, R. J. Nat. Synth. 2022, 1, 439. pmid: 35756523
	(e) Harder, S.; Langer, J. Nat. Rev. Chem. 2023, 7, 843. pmid: 35756523
	(f) Gimferrer, M.; Danes, S.; Vos, E.; Yildiz, C. B.; Corral, I.; Jana, A.; Salvador, P.; Andrada, D. M. Chem. Sci. 2022, 13, 6583. doi: 10.1039/d2sc01401g pmid: 35756523
	(g) Yadav, R.; Sinhababu, S.; Yadav, R.; Kundu, S. Dalton Trans. 2022, 51, 2170. pmid: 35756523
	(h) Boronski, J. T. Dalton Trans. 2024, 53, 33. pmid: 35756523
	(i) Evans, M. J.; Jones, C. Chem. Soc. Rev. 2024, 53, 5054. pmid: 35756523
[6]	Green, S. P.; Jones, C.; Stasch, A. Science 2007, 318, 1754.
[7]	Green, S. P.; Jones, C.; Stasch, A. Angew. Chem., Int. Ed. 2008, 47, 9079.
[8]	Liu, Y.; Li, S.; Yang, X.-J.; Yang, P.; Wu, B. J. Am. Chem. Soc. 2009, 131, 4210.
[9]	(a) Stasch, A.; Jones, C. Dalton Trans. 2011, 40, 5659.
	(b) Jones, C.; Stasch, A. Top. Organomet. Chem. 2013, 45, 73.
	(c) Ma, M.; Wang, W.; Yao, W. Chin. J. Org. Chem. 2016, 36, 72 (in Chinese).
	(马猛涛, 王未凡, 姚薇薇, 有机化学, 2016, 36, 72.) doi: 10.6023/cjoc201507015
[10]	Connelly, N. G.; Geiger, W. E. Chem. Rev. 1996, 96, 877. doi: 10.1021/cr940053x pmid: 11848774
[11]	Wang, W.; Luo, M.; Li, J.; Pullarkat, S. A.; Ma, M. Chem. Commun. 2018, 54, 3042.
[12]	Liu, H.-Y.; Schwamm, R. J.; Neale, S. E.; Hill, M. S.; McMullin, C. L.; Mahon, M. F. J. Am. Chem. Soc. 2021, 143, 17851.
[13]	Liu, H.-Y.; Neale, S. E.; Hill, M. S.; Mahon, M. F.; McMullin, C. L.; Richards, E. Angew. Chem., Int. Ed. 2023, 62, e202213670.
[14]	(a) Ren, W.; Gu, D. Inorg. Chem. 2016, 55, 11962. pmid: 31124671
	(b) Ren, W.; Fang, X.; Sun, W.; Gu, D.; Yu, Y. J. Organomet. Chem. 2017, 842, 47. pmid: 31124671
	(c) Freeman, L. A.; Walley, J. E.; Obi, A. D.; Wang, G.; Dickie, D. A.; Molino, A.; Wilson, D. J. D.; Gilliard, R. J. Inorg. Chem. 2019, 58, 10554. doi: 10.1021/acs.inorgchem.9b01058 pmid: 31124671
[15]	Kaim, W. Inorg. Chem. 2011, 50, 9752.
[16]	Gentner, T. X.; Rösch, B.; Ballmann, G.; Langer, J.; Elsen, H.; Harder, S. Angew. Chem., Int. Ed. 2019, 58, 607. doi: 10.1002/anie.201812051 pmid: 30422354
[17]	Pan, J.; Zhang, L.; He, Y.; Yu, Q.; Tan, G. Organometallics 2021, 40, 3365.
[18]	(a) Jędrzkiewicz, D.; Mai, J.; Langer, J.; Mathe, Z.; Patel, N.; DeBeer, S.; Harder, S. Angew. Chem., Int. Ed. 2022, 61, e202200511.
	(b) Jędrzkiewicz, D.; Langer, J.; Harder, S. Z. Anorg. Allg. Chem. 2022, 648, e202200138.
[19]	Rösch, B.; Gentner, T. X.; Eyselein, J.; Langer, J.; Elsen, H.; Harder, S. Nature 2021, 592, 717.
[20]	Mondal, R.; Evans, M. J.; Rajeshkumar, T.; Maron, L.; Jones, C. Angew. Chem., Int. Ed. 2023, 62, e202308347.
[21]	(a) Buchner, M. R. Chem. Commun. 2020, 56, 8895. pmid: 23572069
	(b) Buchner, M. R. Chem. Eur. J. 2019, 25, 12018. pmid: 23572069
	(c) Perera, L. C.; Raymond, O.; Henderson, W.; Brothers, P. J.; Plieger, P. G. Coord. Chem. Rev. 2017, 352, 264. pmid: 23572069
	(d) Naglav, D.; Buchner, M. R.; Bendt, G.; Kraus, F.; Schulz, S. Angew. Chem., Int. Ed. 2016, 55, 10562. pmid: 23572069
	(e) Iversen, K. J.; Couchman, S. A.; Wilson, D. J. D.; Dutton, J. L. Coord. Chem. Rev. 2015, 297, 40. pmid: 23572069
	(f) Puchta, R. Nat. Chem. 2011, 3, 416. doi: 10.1038/nchem.1033 pmid: 23572069
	(g) Couchman, S. A.; Holzmann, N.; Frenking, G.; Wilson, D. J. D.; Dutton, J. L. Dalton Trans. 2013, 42, 11375. doi: 10.1039/c3dt50563d pmid: 23572069
[22]	Arrowsmith, M.; Braunschweig, H.; Celik, M. A.; Dellermann, T.; Dewhurst, R. D.; Ewing, W. C.; Hammond, K.; Kramer, T.; Krummenacher, I.; Mies, J.; Radacki, K.; Schuster, J. K. Nat. Chem. 2016, 8, 890.
[23]	Paparo, A.; Smith, C. D.; Jones, C. Angew. Chem., Int. Ed. 2019, 58, 11459.
[24]	Wang, G.; Walley, J. E.; Dickie, D. A.; Pan, S.; Frenking, G.; Gilliard, R. J. J. Am. Chem. Soc. 2020, 142, 4560.
[25]	Czernetzki, C.; Arrowsmith, M.; Fantuzzi, F.; Gärtner, A.; Tröster, T.; Krummenacher, I.; Schorr, F.; Braunschweig, H. Angew. Chem., Int. Ed. 2021, 60, 20776. doi: 10.1002/anie.202108405 pmid: 34263524
[26]	Czernetzki, C.; Arrowsmith, M.; Endres, L.; Krummenacher, I.; Braunschweig, H. Inorg. Chem. 2024, 63, 2670.
[27]	Pearce, K. G.; Hill, M. S.; Mahon, M. F. Chem. Commun. 2023, 59, 1453.
[28]	Boronski, J. T.; Crumpton, A. E.; Wales, L. L.; Aldridge, S. Science 2023, 380, 1147. doi: 10.1126/science.adh4419 pmid: 37319227
[29]	Boronski, J. T.; Thomas-Hargreaves, L. R.; Ellwanger, M. A.; Crumpton, A. E.; Hicks, J.; Bekis, D. F.; Aldridge, S.; Buchber, M. R. J. Am. Chem. Soc. 2023, 145, 4408.
[30]	Boronski, J. T.; Crumpton, A. E.; Roper, A. F.; Aldridge, S. Nat. Chem. 2024, 16, 1295.
[31]	Berthold, C.; Maurer, J.; Klerner, L.; Harder, S.; Buchner, M. R. Angew. Chem., Int. Ed. 2024, 63, e202408422.
[32]	(a) Westerhausen, M.; Koch, A.; Görls, H.; Krieck, S. Chem. Eur. J. 2017, 23, 1456.
	(b) Wei, B.; Li, H.; Zhang, W.-X.; Xi, Z. Organometallics 2015, 34, 1339.
	(c) Wei, B.; Liu, L.; Zhang, W.-X.; Xi, Z. Angew. Chem., Int. Ed. 2017, 56, 9188.
	(d) Wei, B.; Zhang, W.-X.; Xi, Z. Dalton Trans. 2018, 47, 12540.
[33]	(a) Wilson, A. S. S.; Hill, M. S.; Mahon, M. F.; Dinoi, C.; Maron, L. Science 2017, 358, 1168.
	(b) Harder, S. Chem. Rev. 2010, 110, 3852.
	(c) Hu, H.; Cui, C. Organometallics 2012, 31, 1208.
	(d) Li, H.; Wang, X.-Y.; Wei, B.; Xu, L.; Zhang, W.-X.; Pei, J.; Xi, Z. Nat. Commun. 2014, 5, 4508.
	(e) Wei, B.; Li, H.; Zhang, W.-X.; Xi, Z. Organometallics 2016, 35, 1458.
	(f) Zhang, X.-Y.; Du, H.-Z.; Zhai, D.-D.; Guan, B.-T. Org. Chem. Front. 2020, 7, 1991.
	(g) Li, T.; McCabe, K. N.; Maron, L.; Leng, X.; Chen, Y. ACS Catal. 2021, 11, 6348.
	(h) Zheng, X.; Rosal, I.; Xu, X.; Yao, Y.; Maron, L.; Xu, X. Inorg. Chem. 2021, 60, 5114.
[34]	(a) Wu, X.; Zhao, L.; Jin, J.; Pan, S.; Li, W.; Jin, X.; Wang, G.; Zhou, M.; Frenking, G. Science 2018, 361, 912.
	(b) Zhao, L.; Pan, S.; Zhou, M.; Frenking, G. Science 2019, 365, 6453.
	(c) Zhou, M.; Frenking, G. Acc. Chem. Res. 2021, 54, 3071.
	(d) Huo, B.; Sun, R.; Jin, B.; Hu, L.; Bian, J.-H.; Guan, X.-L.; Yuan, C.; Lu, G.; Wu, Y.-B. Chem. Commun. 2021, 57, 5806.
[35]	Krieck, S.; Görls, H.; Yu, L.; Reiher, M.; Westerhausen, M. J. Am. Chem. Soc. 2009, 131, 2977. doi: 10.1021/ja808524y pmid: 19193100
[36]	Huang, W.; Diaconescu, P. L. Dalton Trans. 2015, 44, 15360.
[37]	Rösch, B.; Gentner, T. X.; Langer, J.; Färber, C.; Eyselein, J.; Zhao, L.; Ding, C.; Frenking, G.; Harder, S. Science 2021, 371, 1125. doi: 10.1126/science.abf2374 pmid: 33707259
[38]	(a) Li, J.; Yin, J.; Yu, C.; Zhang, W.; Xi, Z. Acta Chim. Sinica 2017, 75, 733 (in Chinese).
	(李嘉鹏, 殷剑昊, 俞超, 张文雄, 席振峰, 化学学报, 2017, 75, 733.) doi: 10.6023/A17040170
	(b) Ma, X.; Lei, M. Prog. Chem. 2013, 25, 1325 (in Chinese).
	(马雪璐, 雷鸣, 化学进展, 2013, 25, 1325.) doi: 10.7536/PC121211
	(c) Fan, Y.; Cheng, J.; Gao, Y.; Shi, M.; Deng, L. Acta Chim. Sinica 2018, 76, 445 (in Chinese).
	(凡一明, 程骏, 高亚飞, 施敏, 邓亮, 化学学报, 2018, 76, 445.) doi: 10.6023/A18030095
[39]	Mondal, R.; Yuvaraj, K.; Rajeshkumar, T.; Maron, L.; Jones, C. Chem. Commun. 2022, 58, 12665.
[40]	(a) Mai, J.; Morasch, M.; Jędrzkiewicz, D.; Langer, J.; Rösch, B.; Harder, S. Angew. Chem., Int. Ed. 2023, 62, e202212463.
	(b) Mai, J.; Rösch, B.; Langer, J.; Grams, S.; Morasch, M.; Harder, S. Eur. J. Inorg. Chem. 2023, 26, e202300421.
[41]	Liu, Y.; Zhu, K.; Chen, L.; Liu, S.; Ren, W. Inorg. Chem. 2022, 61, 20373.
[42]	Wu, L.; Wang, Z.; Liu, Y.; Chen, L.; Ren, W. Dalton Trans. 2023, 52, 7175.
[43]	(a) Shi, X.; Liu, Z.; Cheng, J. Chin. J. Org. Chem. 2019, 39, 1557 (in Chinese). pmid: 28777882
	(石向辉, 刘知洲, 程建华, 有机化学, 2019, 39, 1557.) doi: 10.6023/cjoc201903043 pmid: 28777882
	(b) Shi, X.; Qin, G.; Wang, Y.; Zhao, L.; Liu, Z.; Cheng, J. Angew. Chem., Int. Ed. 2019, 58, 4356. pmid: 28777882
	(c) Jochmann, P.; Davin, J. P.; Spaniol, T. P.; Maron, L.; Okuda, J. Angew. Chem., Int. Ed. 2012, 51, 4452. doi: 10.1002/anie.201200690 pmid: 28777882
	(d) Leich, V.; Spaniol, T. P.; Maron, L.; Okuda, J. Angew. Chem., Int. Ed. 2016, 55, 4794. pmid: 28777882
	(e) Schuhknecht, D.; Lhotzky, C.; Spaniol, T. P.; Maron, L.; Okuda, J. Angew. Chem., Int. Ed. 2017, 56, 12367. doi: 10.1002/anie.201706848 pmid: 28777882
[44]	(a) Mai, J.; Rösch, B.; Patel, N.; Langer, J.; Harder, S. Chem. Sci. 2023, 14, 4724.
	(b) Mai, J.; Maurer, J.; Langer, J.; Harder, S. Nat. Synth. 2024, 3, 368.
[45]	Stegner, P.; Färber, C.; Zenneck, U.; Knüpfer, C.; Eyselein, J.; Wiesinger, M.; Harder, S. Angew. Chem., Int. Ed. 2021, 60, 4252.
[46]	Guan, Y.; Liu, C.; Wang, Q.; Gao, W.; Hansen, H. A.; Guo, J.; Vegge, T.; Chen, P. Angew. Chem., Int. Ed. 2022, 61, e202205805.
[47]	Townrow, O. P. E.; Färber, C.; Zenneck, U.; Harder, S. Angew. Chem., Int. Ed. 2024, 63, e202318428.

低氧化态碱土金属有机化学概述

Overview on Low-oxidation-state Alkaline Earth Organometallic Chemistry

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 32

References 47

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yuhan Liu, Pan Gao. Direct Borylation of Organohalides Using Mechanochemically Generated Calcium-Based Heavy Grignard Reagents (R-CaX) [J]. Acta Chimica Sinica, 2024, 82(11): 1114-1119.
[2]	Min Dai, Gangtie Lei, Zhao Zhang, Zhi Li, Hujun Cao, Ping Chen. Room Temperature Hydrogen Absorption of V₂O₅ Catalyzed MgH₂/Mg^※ [J]. Acta Chimica Sinica, 2022, 80(3): 303-309.
[3]	Xiaolan Xue, Yang Zhang, Meiyu Shi, Tianlin Li, Tianlong Huang, Jiqiu Qi, Fuxiang Wei, Yanwei Sui, Zhong Jin. Recent Progress on Organic Electrode Materials for Nonaqueous Magnesium Secondary Batteries [J]. Acta Chimica Sinica, 2022, 80(12): 1618-1628.
[4]	Wanfei Li, Xin Li, Haiyan Fan, Jianhua Xiao, Qianqian Liu, Miao Cheng, Jing Hu, Tao Wei, Zhengying Wu, Yun Ling, Bo Liu, Yuegang Zhang. Progress of Non-Nucleophilic Electrolytes for Magnesium/Sulfur Battery [J]. Acta Chimica Sinica, 2021, 79(5): 628-640.
[5]	Tang Gong-ao, Mao Kun, Zhang Jing, Lyu Pin, Cheng Xueyi, Wu Qiang, Yang Lijun, Wang Xizhang, Hu Zheng. Hierarchical Nitrogen-doped Carbon Nanocages as High-rate Long-life Cathode Material for Rechargeable Magnesium Batteries [J]. Acta Chimica Sinica, 2020, 78(5): 444-450.
[6]	Maryam Keram, Ma Haiyan. Non-symmetric β-Diketiminate Magnesium Complexes as Initiators for Ring-Opening Polymerization/Copolymerization of Lactide, ε-Caprolactone [J]. Acta Chim. Sinica, 2018, 76(2): 121-132.
[7]	Zhang Changhuan, Li Nianwu, Yao Hurong, Liu Lin, Yin Yaxia, Guo Yuguo. Synthesis of Sn Nanoparticles/Graphene Nanosheet Hybrid Electrode Material with Three-Dimensional Conducting Network for Magnesium Storage [J]. Acta Chim. Sinica, 2017, 75(2): 206-211.
[8]	Xu Yanglei, Meng Zheyi, Zhai Jin. pH and Calcium Cooperative Regulation Nanofluidic Gating Device [J]. Acta Chim. Sinica, 2016, 74(6): 538-544.
[9]	Wu Zhicheng, Pan Danmei, Chen Zhi, Lin Zhang. Synthesis of Flaky Flame-retardant Magnesium Hydroxide with High Dispersion [J]. Acta Chimica Sinica, 2012, 70(19): 2045-2048.
[10]	Li Wenzhuo, Huang Fanglun, Wang Jianlong. A New Calcium Electrode Based on the Composite Thioacetamide/attapulgite as Ionophore [J]. Acta Chimica Sinica, 2012, 70(18): 1963-1968.
[11]	Lv Jian, Zhong Xingren, Cheng Jin-Pei, Luo Sanzhong. Asymmetric Binary-Acid Catalysis in the Inverse-Electron-Demanding Hetero-Diels-Alder Reaction of 3,4-Dihydro-2H-Pyran [J]. Acta Chimica Sinica, 2012, 70(14): 1518-1522.
[12]	Fu Xiaowei, Ni Zheming, Liu Jiao. Surface Characterization of Copper-Aluminum-Magnesium Hydrotalcites Investigated by Inverse Gas Chromatography [J]. Acta Chimica Sinica, 2012, 70(08): 968-972.
[13]	GE Hong-Hua, WEI Cheng-Jun, GONG Xiao-Ming, XU Xue-Min, TAO Jie-Ting, YAO Xiu-Ping. Effect of Electromagnetic Treatment on Sedimentation and Adhesion Behavior of Calcium Carbonate Particles Formed in Aqueous Solution [J]. Acta Chimica Sinica, 2011, 69(19): 2313-2318.
[14]	PAN Deng-Ke, ZHANG Hui. Synthesis and Drug Release Behavior of Magnetic Nanoparicles Based on Layered Double Hydroxide for Magnetic Drug Targeting [J]. Acta Chimica Sinica, 2011, 69(13): 1545-1552.
[15]	WANG Li-Dong, MA Yong-Liang, HAO Ji-Ming, ZHANG Wen-Di, YUAN Gang. Mechanism and Effect of a Phenol Inhibitor on the Oxidation Kinetics of Magnesium Sulfite [J]. Acta Chimica Sinica, 2011, 69(10): 1160-1166.