Studies on Structural Engineering and Intercomponent Interactions of Zeolite-Based Industrial Multicomponent Catalysts★

doi:10.6023/A25050163

Acta Chimica Sinica ›› 2025, Vol. 83 ›› Issue (9): 1072-1088.DOI: 10.6023/A25050163 Previous Articles Next Articles

Review

沸石基工业多组元催化剂的结构设计及组元间相互作用研究^★

徐亦璞^a^,^b, 徐舒涛^b^,^*(), 魏迎旭^b, 阎子峰^a^,^*(), 刘中民^b

^a 中国石油大学(华东) 重质油全国重点实验室青岛 266580
^b 中国科学院大连化学物理研究所低碳催化与工程研究中心大连 116023

投稿日期:2025-05-12 发布日期:2025-07-04

作者简介:

徐亦璞, 中国石油大学(华东)重质油全国重点实验室博士生, 中国科学院大连化学物理研究所联合培养博士生. 本科毕业于中国石油大学(华东)化学化工学院. 主要研究方向为多级孔沸石的合成及催化应用和沸石催化剂的扩散及动力学.

徐舒涛, 中国科学院大连化学物理研究所研究员, 优青. 2004年本科毕业于复旦大学化学系, 2010年博士毕业于中国科学院大连化学物理研究所. 现为大连化学物理研究所低碳催化技术国家工程研究中心科研骨干. 2016年获第16届国际催化大会青年科学家奖, 2020年获国家自然科学基金委优秀青年基金资助, 2023年获中国化学会分子筛青年奖. 主要研究方向为原位固体核磁谱学技术在分子筛催化中的应用.

魏迎旭, 中国科学院大连化学物理研究所研究员. 1993年于上海交通大学获得学士学位, 2001年于中国科学院大连化学物理研究获得博士学位, 毕业后在中国科学院大连化学物理研究所工作, 期间于2003~2004年赴比利时Namur大学进行博士后研究. 现为低碳催化技术国家工程研究中心研究员, 催化反应机理和新反应探索研究组组长. 从事分子筛催化、甲醇制烯烃、烷烃转化及二氧化碳耦合烷烃转化制高值化学品的基础和应用研究. 入选科技部创新人才推进计划中青年科技创新领军人才、大连化学物理研究所首席研究员及张大煜优秀学者等.

阎子峰, 中国石油大学(华东)重质油全国重点实验室教授. 于兰州大学化学系获得学士、硕士学位, 于中国科学院兰州化学物理研究所获得博士学位. 目前为中国石油大学(华东)二级教授, 同时兼任中国化学会催化委员会委员、中国化学会分子筛委员会委员、中国化工学会理事及山东省化学化工学会常务理事兼催化专业委员会主任委员. 二十多年来, 主持承担30余项国家/山东省重点研发项目、国家自然科学基金重点项目等国家、省部级重大研究课题和攻关项目, 承担5项与Shell、KACST等的国际合作项目, 先后实现多项技术的工业化. 主要研究方向为催化材料与催化剂的结构设计、定向合成及催化应用, 新型电极材料及新能源领域应用研究.

刘中民, 中国工程院院士, 中国科学院大连化学物理研究所所长、低碳催化技术国家工程研究中心主任、国家能源低碳催化与工程研发中心主任. 1983年于郑州大学获得学士学位, 1986年于中国科学院大连化学物理研究所获得硕士学位业, 1990年在中国科学院大连化学物理研究所获得博士学位, 1996年3月至1996年10月, 在法国科研中心CNRS418 (Montpellier)开展博士后工作. 刘中民院士长期从事应用催化研究, 作为技术总负责人合作完成了多项创新成果并实现产业化. 完成了世界首次甲醇制烯烃(DMTO)技术工业性试验及首次工业化, 完成了世界首套10万吨/年煤基乙醇(DMTE)工业示范项目, 引领了我国新兴煤制大宗化学品和清洁燃料产业的发展.

^★ “中国青年化学家”专辑.

基金资助:
国家自然科学基金(22241801); 国家自然科学基金(22288101); 国家自然科学基金(22022202); 国家自然科学基金(22032005); 大连市杰出青年科学家基金(2021RJ01); 辽宁国际联合实验室(2024JH2/102100005); 中国石油大学(华东)研究生创新基金及中央高校基本科研业务费专项资金(24CX04004A)

Studies on Structural Engineering and Intercomponent Interactions of Zeolite-Based Industrial Multicomponent Catalysts^★

Yipu Xu^a^,^b, Shutao Xu^b^,^*(), Yingxu Wei^b, Zifeng Yan^a^,^*(), Zhongmin Liu^b

^a State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao 266580
^b National Engineering Research Center of Lower-Carbon Catalysis Technology, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023

Received:2025-05-12 Published:2025-07-04
Contact: * E-mail: xushutao@dicp.ac.cn;zfyancat@upc.edu.cn
About author:
^★ For the VSI “Rising Stars in Chemistry”.
Supported by:
National Natural Science Foundation of China(22241801); National Natural Science Foundation of China(22288101); National Natural Science Foundation of China(22022202); National Natural Science Foundation of China(22032005); Dalian Outstanding Young Scientist Foundation(2021RJ01); Liaoning International Joint Laboratory Project(2024JH2/102100005); Innovation Fund Project for Graduate Student of China University of Petroleum (East China) and the Fundamental Research Funds for the Central Universities(24CX04004A)

The ultimate goal of catalysis research is to enhance catalytic efficiency under industrial conditions. Industrial catalysts are typically complex multicomponent systems, comprising zeolitic components integrated with non-zeolitic components such as silica, alumina, amorphous aluminosilicate, clay, etc. Their catalytic performance is not only determined by the intrinsic properties of each component, but also is strongly influenced by the nature and extent of intercomponent interactions. However, most academic studies have focused primarily on tailoring zeolitic components, while the critical roles of non-zeolitic components and their interactions with zeolitic components were overlooked. This oversight has contributed to a persistent gap between laboratory research and practical industrial catalyst design. This review focuses on the structural integration and functional synergy between zeolitic and non-zeolitic components in industrial catalysts, with particular emphasis on fluid catalytic cracking systems as a representative case. We discuss the hierarchical and cooperative behavior of multicomponent catalytic architectures and highlight three key types of zeolitic and non-zeolitic components interactions: (1) aluminum species migration and redistribution and its influence on Brønsted and Lewis acidity; (2) cation exchange and proximity-induced modulation of acid sites between components; and (3) pore network matching and interconnectivity, which critically influence molecular diffusion and transport efficiency. By establishing correlations of structure-property-reactivity between the interface of zeolitic and non-zeolitic components, this review provides a conceptual framework to better understand and control these complex systems. We further propose future directions for the rational design of integrated industrial catalysts, emphasizing the use of advanced characterization techniques and computational simulations to unravel microscopic interaction mechanisms. These insights are expected to guide the development of more efficient, energy-saving, and environmentally benign catalytic materials for industrial applications.

Key words: zeolite catalytic material, industrial catalyst, fluid catalytic cracking, intercomponent interaction, diffusion

Cite this article

Yipu Xu, Shutao Xu, Yingxu Wei, Zifeng Yan, Zhongmin Liu. Studies on Structural Engineering and Intercomponent Interactions of Zeolite-Based Industrial Multicomponent Catalysts^★[J]. Acta Chimica Sinica, 2025, 83(9): 1072-1088.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 12

Figure 1. Current status of the refining and petrochemical industry: (a) global energy outlook by OPEC, (b) refining capacity data (sourced from the National Bureau of Statistics of China), and (c) typical integrated refining and petrochemical process flow (sourced from UOP)

Figure 3. Structure and composition of integrated catalysts for low-carbon olefin-oriented catalytic cracking

Figure 5. Formation of new acid sites induced by intercomponent interactions[42-43]: (a, b) difference spectra before and after CO saturation on zeolite and its extrudates[43] [(a) OH region (b) CO region] (Copyright 2020, with permission from Elsevier) and (c) 27Al-{29Si} J-HMQC NMR spectra on extrudates[42] (Copyright 2021, American Chemical Society)

Figure 6. Effect of silica as a binder on the acidity of catalysts[55-57]: (a) 3D confocal fluorescence microscopy images of the ZSM-5-binder-bound pellets combined with either SiO2 (left) or Al2O3 (right) as non-zeolitic components[55] (Copyright 2019, Bert M. Weckhuysen, Martijn Burgers, Anton-Jan Bons, et al. Published by Wiley-VCH Verlag GmbH & Co. KGaA), (b) 27Al solid state MAS NMR of multicomponent catalysts[56] (Copyright 2018 Elsevier B. V. All right reserved), and (c) FT-IR of NH3 adsorbed on different multicomponent catalyst (NaY-SiO2, NaY, and SiO2)[57] (Copyright 2015, American Chemical Society)

Figure 7. Migration of metal cations between zeolitic and non-zeolitic components: (a) MTH lifetime over milled hierarchical ZSM-5 admixtures with attapulgite, HCl-treated attapulgite, kaolin, and MgO-doped kaolin,[64] (b) differences in average product selectivity compared with respect to the corresponding physical mixtures,[64] (Copyright 2014, American Chemical Society) and (c) visualizing early stages of deactivation in zeolite-based shaped catalyst bodies by confocal fluorescence microscopy (CFM) images[66] (Copyright 2023 The Nikolaos Nikolopoulos, Luke A. Parker, Maurits W. Vuijk, Bert M. Weckhuysen. Published by Elsevier Inc)

Figure 8. Effect of metal particle deposition sites on the performance of composite catalysts: (a) n-heptane conversion against the reaction temperature, and (b) yields of total C7 isomers and cracking products[72] (Copyright 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) and (c) impact of nanoscale intimacy on hydrocracking activity and selectivity[73] (Copyright 2015, Springer Nature Limited)

Figure 9. Effect of incorporating non-zeolitic components on the pore hierarchy of the overall catalyst: (a) pore hierarchy reorganization induced by non-zeolitic components[4] (Copyright 2019, American Chemical Society), (b) construction of multiscale pores with well-matched pore sizes from macropores to micropores enhances mass transport[22] (Copyright 2022, Sun, Ming-Hui; Gao Shu-shu 2022. Published by Oxford University Press on behalf of China Science Publishing) and (c) significant diffusion limitations arise from poor pore-size matching between components

Figure 10. (a) Schematic illustration of pore interconnectivity alteration induced by orientation mismatch between zeolitic and non-zeolitic components[81,84] [Left panel shows aligned orientation between the micropores of the zeolitic component (blue) and the mesopores of the non-zeolitic component (pink). Right panel shows a misaligned pore orientation between the zeolitic and non-zeolitic components], (b) frequency response (FR) technique for identifying zeolitic and non-zeolitic components interfacial resistance[81] (Copyright © 2014 Published by Elsevier B.V. All rights reserved), and (c) surface mass transfer resistance caused by blocked pore openings on zeolite crystals[84] (Copyright 2011 Aptara Inc. All rights reserved)

Figure 11. Crucial roles of pore interconnectivity between zeolitic and non-zeolitic components in enhancing diffusion and catalytic efficiency[34]: (a) Identification of multicomponent hierarchical pore network connectivity by HP 129Xe NMR, (b) relating pore interconnectivity to diffusion in multicomponent model catalysts by time-resolved rapid-scan in situ FTIR technology, and (c) catalytic efficiency assessment of multicomponent model catalysts (Copyright 2025, American Chemical Society)

Figure 12. (a) Schematic of the effect of the spatial distribution between zeolitic and non-zeolitic components on diffusion pathways[75-76,95] (The left panel illustrates a loosely packed configuration of non-zeolitic components, whereas the right panel shows more uniformly coated), (b) guest molecules in nano-zeolite and the impact of surface covering with small silica particles[75]. (Copyright 2019, Zhou, Jian; Fan, Wei 2019. Published by Oxford University Press on behalf of China Science Publishing) and (c, d) surface barrier schemes for mass transport in zeolitic component[76,95] (Copyright 2021, Shen Hu, Junru Liu, Guanghua Ye, et al. Angewandte Chemie International Edition published by Wiley VCH GmbH. Copyright 2011, American Chemical Society)

References 96

[1]	Xu, Y.-H. Sci. Sin.: Chim. 2014, 44, 13 (in Chinese).
	(许友好, 中国科学: 化学, 2014, 44, 13.)
[2]	Xiong, H.; Liang, X.-Y.; Zhang, C.-X.; Bai, H.-L.; Fan, X.-Y.; Wei, F. CIESC J. 2023, 74, 86 (in Chinese).
	(熊昊, 梁潇予, 张晨曦, 白浩隆, 范晓宇, 魏飞, 化工学报, 2023, 74, 86.) doi: 10.11949/0438-1157.20221188
[3]	Kennes, K.; Kubarev, A.; Demaret, C.; Treps, L.; Delpoux, O.; Rivallan, M.; Guillon, E.; Méthivier, A.; de Bruin, T.; Gomez, A.; Harbuzaru, B.; Roeffaers, M. B. J.; Chizallet, C. ACS Catal. 2022, 12, 6794.
[4]	Whiting, G. T.; Chung, S.-H.; Stosic, D.; Chowdhury, A. D.; van der Wal, L. I.; Fu, D.; Zecevic, J.; Travert, A.; Houben, K.; Baldus, M.; Weckhuysen, B. M. ACS Catal. 2019, 9, 4792. doi: 10.1021/acscatal.9b00151
[5]	Yang, K.; Zhang, D.; Zou, M.; Yu, L.; Huang, S. ChemCatChem 2021, 13, 1414.
[6]	Ren, F.-J.; Ling, Y.-S.; Wang, Q.-Z. Mod. Chem. Ind. 2011, 31, 13 (in Chinese).
	(任夫健, 凌永社, 王庆志, 现代化工, 2011, 31, 13.)
[7]	Mitchell, S.; Michels, N. L.; Perez-Ramirez, J. Chem. Soc. Rev. 2013, 42, 6094. doi: 10.1039/c3cs60076a pmid: 23648466
[8]	Vogt, E. T.; Weckhuysen, B. M. Chem. Soc. Rev. 2015, 44, 7342. doi: 10.1039/c5cs00376h pmid: 26382875
[9]	Bai, P.; Etim, U. J.; Yan, Z.; Mintova, S.; Zhang, Z.; Zhong, Z.; Gao, X. Catal. Rev. 2018, 61, 333.
[10]	Wang, B.; Han, C.; Zhang, Q.; Li, C.; Yang, C.; Shan, H. Energy Fuels 2015, 29, 5701.
[11]	den Hollander, M. A.; Wissink, M.; Makkee, M.; Moulijn, J. A. Appl. Catal., A 2002, 223, 85.
[12]	Zhao, Q.; Li, F.; Zhang, P.-H.; Liu, Y.-M. Acta Chim. Sinica 2024, 82, 1013 (in Chinese). doi: 10.6023/A24070216
	(赵勤, 李芳, 张鹏鹤, 刘月明, 化学学报, 2024, 82, 1013.) doi: 10.6023/A24070216
[13]	Zhang, H.-D.; Lan, X.-Y.; Cheng, P. Acta Chim. Sinica 2023, 81, 100 (in Chinese).
	(张红丹, 兰欣雨, 程鹏, 化学学报, 2023, 81, 100.) doi: 10.6023/A22100420
[14]	Feng, R.; Liu, S.; Bai, P.; Qiao, K.; Wang, Y.; Al-Megren, H. A.; Rood, M. J.; Yan, Z. J. Phys. Chem. C 2014, 118, 6226.
[15]	Mitchell, S.; Michels, N. L.; Kunze, K.; Perez-Ramirez, J. Nat. Chem. 2012, 4, 8251.
[16]	Hargreaves, J. S. J.; Munnoch, A. L. Catal. Sci. Technol. 2013, 3, 1165.
[17]	Xu, Q.; Ren, F.; Zhu, Y.-X. Pet. Process. Petrochem. 2017, 48, 57 (in Chinese).
	(徐奇, 任飞, 朱玉霞, 石油炼制与化工, 2017, 48, 57.)
[18]	Huo, L.-B. Chem. Eng. Des. Commun. 2019, 45, 214 (in Chinese).
	(霍连波, 化工设计通讯, 2019, 45, 214.)
[19]	Zhang, Y.-W.; Shen, Z.-F. Chem. Enterp. Manage. 2018, 30, 94 (in Chinese).
	(张有文, 申志峰, 化工管理, 2018, 30, 94.)
[20]	Peng, P.; Gao, X. H.; Yan, Z. F.; Mintova, S. Natl. Sci. Rev. 2020, 7, 1726. doi: 10.1093/nsr/nwaa184 pmid: 34691504
[21]	Lee, S.; Park, Y.; Choi, M. ACS Catal. 2024, 14, 2031.
[22]	Sun, M. H.; Gao, S. S.; Hu, Z. Y.; Barakat, T.; Liu, Z.; Yu, S.; Lyu, J. M.; Li, Y.; Xu, S. T.; Chen, L. H.; Su, B. L. Natl. Sci. Rev. 2022, 9, nwac236.
[23]	Duan, J.; Chen, W.; Wang, C.; Wang, L.; Liu, Z.; Yi, X.; Fang, W.; Wang, H.; Wei, H.; Xu, S.; Yang, Y.; Yang, Q.; Bao, Z.; Zhang, Z.; Ren, Q.; Zhou, H.; Qin, X.; Zheng, A.; Xiao, F. S. J. Am. Chem. Soc. 2022, 144, 14269.
[24]	Mendoza-Castro, M. J.; Qie, Z.; Fan, X.; Linares, N.; García- Martínez, J. Nat. Commun. 2023, 14, 1256. doi: 10.1038/s41467-023-36502-3 pmid: 36878918
[25]	Sun, M. H.; Chen, L. H.; Yu, S.; Li, Y.; Zhou, X. G.; Hu, Z. Y.; Sun, Y. H.; Xu, Y.; Su, B. L. Angew. Chem., Int. Ed. 2020, 59, 19582.
[26]	Zhang, J.; Ren, L.; Zhang, A.; Guo, X.; Song, C. Mat. Chem. Front. 2024, 8, 595.
[27]	Choi, M.; Na, K.; Kim, J.; Sakamoto, Y.; Terasaki, O.; Ryoo, R. Nature 2009, 461, 246.
[28]	Hong, M.; Gao, J.-Q.; Li, T.; Yang, S.-H. Acta Chim. Sinica 2023, 81, 937 (in Chinese). doi: 10.6023/A23040177
	(洪梅, 高金强, 李彤, 杨世和, 化学学报, 2023, 81, 937.) doi: 10.6023/A23040177
[29]	Chen, W.; Han, D.; Sun, X.; Li, C. Fuel 2013, 106, 498.
[30]	Falco, M.; Retuert, J.; Hidrobo, A.; Covarrubias, C.; Araya, P.; Sedran, U. Appl. Catal., A 2009, 366, 269.
[31]	Aguado, J.; Sotelo, J.; Serrano, D.; Calles, J.; Escola, J. Energy Fuels 1997, 11, 1225.
[32]	Liu, Z.; Wang, Y.; Xie, Z. Chin. J. Catal. 2012, 33, 22.
[33]	Zhang, K.; Jiang, X.; Forte, M. J.; Sun, M.; AlAbdullah, M.; AlAmer, M.; Aljishi, M.; AlSayed, E.; AlSadat, W.; Gates, B. C.; Katz, A. Catal. Sci. Technol. 2024, 14, 4740.
[34]	Xu, Y.; Peng, P.; Wang, H.; Xiong, H.; Xu, Z.; Chen, X.; Li, Y.; Zheng, A.; Wei, Y.; Yan, Z.; Xu, S.; Liu, Z. J. Am. Chem. Soc. 2025, 147, 18550.
[35]	Nikolopoulos, N.; Wickramasinghe, A.; Whiting, G. T.; Weckhuysen, B. M. Catal. Sci. Technol. 2023, 13, 862.
[36]	Bhat, Y. S.; Das, J.; Halgeri, A. B. Appl. Catal., A 1995, 122, 161.
[37]	Wu, Y.; Wang, N.; Chen, E.; Feng, H.; Fan, D.; Yu, Y.; Wang, L.; Ji, T.; Yu, Z.; Han, J.; Wei, Y.; Liu, Z. ACS Catal. 2025, 15, 4147.
[38]	Halgeri, A. B.; Das, J. Catal. Today 2002, 73, 65.
[39]	Liu, B.; Zhu, X.; Zhao, J.; Wang, D.; Ma, W. Catalysts 2021, 11, 1140.
[40]	Zhou, S.; Zhang, C.; Li, Y.; Luo, Y.; Shu, X. Ind. Eng. Chem. Res. 2020, 59, 5576.
[41]	Chen, X.-D.; Li, X.-G.; Li, H.; Han, J.-J.; Xiao, W.-D. Chem. Eng. Sci. 2018, 192, 1081.
[42]	Lakiss, L.; Kouvatas, C.; Gilson, J.-P.; Valtchev, V.; Mintova, S.; Fernandez, C.; Bedard, R.; Abdo, S.; Jeffery, B. J. Phys. Chem. C 2021, 125, 20028.
[43]	Lakiss, L.; Gilson, J.-P.; Valtchev, V.; Mintova, S.; Vicente, A.; Vimont, A.; Bedard, R.; Abdo, S.; Bricker, J. Microporous Mesoporous Mat. 2020, 299, 110114.
[44]	Rogala, O.; Tarach, K. A.; Lakiss, L.; Kordek, A.; Valtchev, V.; Gilson, J.-P.; Góra-Marek, K. Appl. Catal.,B 2025, 365, 124893.
[45]	Whiting, G. T.; Chowdhury, A. D.; Oord, R.; Paalanen, P.; Weckhuysen, B. M. Faraday Discuss. 2016, 188, 369. doi: 10.1039/c5fd00200a pmid: 27101314
[46]	Velthoen, M. E. Z.; Lucini Paioni, A.; Teune, I. E.; Baldus, M.; Weckhuysen, B. M. Chem.-Eur. J. 2020, 26, 11995.
[47]	Shihabi, D. S.; Garwood, W. E.; Chu, P.; Miale, J. N.; Lago, R. M.; Chu, C. T.; Chang, C. D. J. Catal. 1985, 93, 471.
[48]	Ishihara, A.; Tsuchimori, Y.; Hashimoto, T. RSC Adv. 2021, 11, 19864. doi: 10.1039/d1ra02677a pmid: 35479253
[49]	Ishihara, A.; Kobayashi, M.; Hashimoto, T. Biomass Convers. Biorefin. 2023, 13, 10711.
[50]	Ishihara, A.; Kanamori, S.; Hashimoto, T. ACS Omega 2021, 6, 5509. doi: 10.1021/acsomega.0c05855 pmid: 33681592
[51]	Ishihara, A.; Ninomiya, M.; Hashimoto, T.; Nasu, H. J. Anal. Appl. Pyrolysis 2020, 150, 104876.
[52]	Ishihara, A.; Matsuura, S.; Hayashi, F.; Suemitsu, K.; Hashimoto, T. Energy Fuels 2020, 34, 7448.
[53]	Ishihara, A.; Mori, K.; Mori, K.; Hashimoto, T.; Nasu, H. Catal. Sci. Technol. 2019, 9, 3614. doi: 10.1039/c9cy00693a
[54]	Itani, L.; Valtchev, V.; Patarin, J.; Rigolet, S.; Gao, F.; Baudin, G. Microporous Mesoporous Mater. 2011, 138, 157.
[55]	Verkleij, S. P.; Whiting, G. T.; Pieper, D.; Parres Esclapez, S.; Li, S.; Mertens, M. M.; Janssen, M.; Bons, A. J.; Burgers, M.; Weckhuysen, B. M. ChemCatChem 2019, 11, 4788. doi: 10.1002/cctc.201900777
[56]	Etim, U. J.; Bai, P.; Wang, Y.; Subhan, F.; Liu, Y.; Yan, Z. Appl. Catal., A 2019, 571, 137.
[57]	Chen, N.-Y.; Liu, M.-C.; Yang, S.-C.; Sheu, H.-S.; Chang, J.-R. Ind. Eng. Chem. Res. 2015, 54, 8456.
[58]	Alba-Rubio, A. C.; Fierro, J. L. G.; León-Reina, L.; Mariscal, R.; Dumesic, J. A.; Granados, M. L. Appl. Catal., B 2017, 202, 269.
[59]	Deng, X.; Lin, D.; Xu, Y.; Feng, X.; Chen, D.; Yang, C.; Shan, H. Chem. Eng. J. 2024, 487, 150338.
[60]	Wang, Y.; Li, L.; Bai, R.; Gao, S.; Feng, Z.; Zhang, Q.; Yu, J. Chin. J. Catal. 2021, 42, 2189.
[61]	Bregante, D. T.; Johnson, A. M.; Patel, A. Y.; Ayla, E. Z.; Cordon, M. J.; Bukowski, B. C.; Greeley, J.; Gounder, R.; Flaherty, D. W. J. Am. Chem. Soc. 2019, 141, 7302. doi: 10.1021/jacs.8b12861 pmid: 30649870
[62]	Xu, H.; Guan, Y.; Lu, X.; Yin, J.; Li, X.; Zhou, D.; Wu, P. ACS Catal. 2020, 10, 4813.
[63]	Wang, L.; Sun, J.; Meng, X.; Zhang, W.; Zhang, J.; Pan, S.; Shen, Z.; Xiao, F.-S. Chem. Commun. 2014, 50, 2012.
[64]	Michels, N.-L.; Mitchell, S.; Pérez-Ramírez, J. ACS Catal. 2014, 4, 2409.
[65]	Yilmaz, B.; Müller, U.; Feyen, M.; Maurer, S.; Zhang, H.; Meng, X.; Xiao, F.-S.; Bao, X.; Zhang, W.; Imai, H.; Yokoi, T.; Tatsumi, T.; Gies, H.; De Baerdemaeker, T.; De Vos, D. Catal. Sci. Technol. 2013, 3, 2580.
[66]	Nikolopoulos, N.; Parker, L. A.; Vuijk, M. W.; Weckhuysen, B. M. Microporous Mesoporous Mater. 2023, 354, 112553.
[67]	Mirena, J. I.; Thybaut, J. W.; Marin, G. B.; Martens, J. A.; Galvita, V. V. Ind. Eng. Chem. Res. 2021, 60, 6357.
[68]	Xu, X.-P.; Fan, K.; Zhao, S.-Z.; Li, J.; Gao, S.; Wu, Z.-B.; Meng, X.-J.; Xiao, F.-S. Acta Chim. Sinica 2023, 81, 1108 (in Chinese).
	(徐续盼, 范凯, 赵胜泽, 李健, 高珊, 吴忠标, 孟祥举, 肖丰收, 化学学报, 2023, 81, 1108.) doi: 10.6023/A23040175
[69]	Guisnet, M. Catal. Today 2013, 218-219, 123.
[70]	Ran, H.; Zhang, S.; Ni, W.; Jing, Y. Chem. Sci. 2024, 15, 795.
[71]	Batalha, N.; Pinard, L.; Bouchy, C.; Guillon, E.; Guisnet, M. J. Catal. 2013, 307, 122.
[72]	Cheng, K.; van der Wal, L. I.; Yoshida, H.; Oenema, J.; Harmel, J.; Zhang, Z.; Sunley, G.; Zecevic, J.; de Jong, K. P. Angew. Chem., Int. Ed. 2020, 59, 3592.
[73]	Zecevic, J.; Vanbutsele, G.; de Jong, K. P.; Martens, J. A. Nature 2015, 528, 245.
[74]	Li, Y.; Wang, M.; Liu, S.; Wu, F.; Zhang, Q.; Zhang, S.; Cheng, K.; Wang, Y. ACS Catal. 2022, 12, 8793.
[75]	Zhou, J.; Fan, W.; Wang, Y.; Xie, Z. Natl. Sci. Rev. 2020, 7, 1630.
[76]	Qi, X.; Vattipalli, V.; Zhang, K.; Bai, P.; Dauenhauer, P. J.; Fan, W. Langmuir 2019, 35, 12407.
[77]	Hu, S.; Liu, J.; Ye, G.; Zhou, X.; Coppens, M. O.; Yuan, W. Angew. Chem., Int. Ed. 2021, 60, 14394.
[78]	Peng, S.; Gao, M.; Li, H.; Yang, M.; Ye, M.; Liu, Z. Angew. Chem., Int. Ed. 2020, 59, 21945.
[79]	Rao, S. M.; Saraçi, E.; Gläser, R.; Coppens, M.-O. Chem. Eng. J. 2017, 329, 45.
[80]	Zhang, Q.; Weng, J.; Wang, Y.; Ye, G.; Shu, Z.; Zhou, X. Ind. Eng. Chem. Res. 2022, 61, 6354.
[81]	Qin, Y.; Gao, X.; Zhang, H.; Zhang, S.; Zheng, L.; Li, Q.; Mo, Z.; Duan, L.; Zhang, X.; Song, L. Catal. Today 2015, 245, 147.
[82]	Chang, C.-C.; Teixeira, A. R.; Li, C.; Dauenhauer, P. J.; Fan, W. Langmuir 2013, 29, 13943.
[83]	Hibbe, F.; Chmelik, C.; Heinke, L.; Pramanik, S.; Li, J.; Ruthven, D. M.; Tzoulaki, D.; Kärger, J. J. Am. Chem. Soc. 2011, 133, 2804.
[84]	Heinke, L.; Kärger, J. Phys. Rev. Lett. 2011, 106, 074501.
[85]	Vattipalli, V.; Qi, X.; Dauenhauer, P. J.; Fan, W. Chem. Mater. 2016, 28, 7852.
[86]	Sastre, G.; Kärger, J.; Ruthven, D. M. J. Phys. Chem. C 2018, 122, 7217.
[87]	Sastre, G.; Kärger, J.; Ruthven, D. M. J. Phys. Chem. C 2019, 123, 19596.
[88]	Combariza, A. F.; Sastre, G. J. Phys. Chem. C 2011, 115, 13751.
[89]	Zimmermann, N. E. R.; Smit, B.; Keil, F. J. J. Phys. Chem. C 2012, 116, 18878.
[90]	Bonilla, M. R.; Valiullin, R.; Kärger, J.; Bhatia, S. K. J. Phys. Chem. C 2014, 118, 14355.
[91]	Dai, W.; Scheibe, M.; Li, L.; Guan, N.; Hunger, M. J. Phys. Chem. C 2012, 116, 2469.
[92]	Luo, X. L.; Guo, J. L.; Chang, P. M.; Qian, H. M.; Pei, F.; Wang, W.; Miao, K. K.; Guo, S. F.; Feng, G. D. Sep. Purif. Technol. 2020, 239, 9.
[93]	Peng, P.; Stosic, D.; Aitblal, A.; Vimont, A.; Bazin, P.; Liu, X.-M.; Yan, Z.-F.; Mintova, S.; Travert, A. ACS Catal. 2020, 10, 6822.
[94]	Qi, X.; Vattipalli, V.; Dauenhauer, P. J.; Fan, W. Chem. Mater. 2018, 30, 2353.
[95]	Gobin, O. C.; Reitmeier, S. J.; Jentys, A.; Lercher, J. A. J. Phys. Chem. C. 2011, 115, 1171.
[96]	Liu, X.; Wang, C.; Zhou, J.; Liu, C.; Liu, Z.; Shi, J.; Wang, Y.; Teng, J.; Xie, Z. Chem. Soc. Rev. 2022, 51, 8174.

沸石基工业多组元催化剂的结构设计及组元间相互作用研究^★

Studies on Structural Engineering and Intercomponent Interactions of Zeolite-Based Industrial Multicomponent Catalysts^★

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 12

References 96

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Wenjie Wei, Wenlong Chen, Xiaobin Dai, Li-Tang Yan. Theory of Anomalous Diffusion Dynamics in Biomacromolecular Media^★ [J]. Acta Chimica Sinica, 2023, 81(8): 967-978.
[2]	Liu Bei, Lian Yuanhui, Li Zhi, Chen Guangjin. Molecular Simulation of Drug Adsorption and Diffusion in Bio-MOFs [J]. Acta Chimica Sinica, 2014, 72(8): 942-948.
[3]	Yang Siqi, Zhang Tianran, Tao Zhanliang, Chen Jun. First-principles Study on Metal-doped LiNi_0.5Mn_1.5O₄ as a Cathode Material for Rechargeable Li-Ion Batteries [J]. Acta Chimica Sinica, 2013, 71(07): 1029-1034.
[4]	Liu Bei, Tang Lixing, Lian Yuanhui, Li Zhi, Sun Changyu, Chen Guangjin. Study on Separation Performance of Metal-organic Frameworks with Interpenetration and Mixed-ligand [J]. Acta Chimica Sinica, 2013, 71(06): 920-928.
[5]	Wu Xuanjun, Yang Xu, Song Jie, Cai Weiquan. Molecular Simulation of Adsorption and Diffusion of CH₄ and H₂ in ZIF-8 Material [J]. Acta Chimica Sinica, 2012, 70(24): 2518-2524.
[6]	Chen Cong, Li Weizhong, Song Yongchen, Weng Lindong, Zhang Ning. Effects of Glycerol Concentrations on Self-diffusion Coefficients of Glycerol in Glycerol-Water-Sodium Chloride Ternary Solutions [J]. Acta Chimica Sinica, 2012, 70(08): 1043-1046.
[7]	Lu Xiaoting, Li Donglin, Fan Xiaoyong, Zhao Peng, Gou Lei, Li Yan, Li Qian, Wang Jing. Study on Structure and Rate Performance of LiFePO₄/C Composite Cathode Material via Na Doping [J]. Acta Chimica Sinica, 2012, 70(03): 223-228.
[8]	JIANG Jun, ZHANG Jun-Xi, LU Jin-Liang, QIAN Sheng-Jie, WU Yong-Cheng, WANG Kun, QU Wen-Jun. Electrochemical Behavior of the Rebar during Re-alkalization Treatment [J]. Acta Chimica Sinica, 2011, 69(20): 2347-2352.
[9]	DU Hai-Long, ZHANG Yong, SHENG Min-Qi, LIU Wei-Dong, ZHONG Qing-Dong, WANG Yi, ZHOU Qiong-Yu. Study on Electrochemistry of Oxide Films Formed on the Surface of Cobalt-tungsten Alloy Coatings in Alkali Solution [J]. Acta Chimica Sinica, 2011, 69(08): 881-888.
[10]	LV Jian-Yi, WENG Qing-Long. Distribution Characteristics of Gas Temperature and Soot Fraction Volume in Ethylene/air Inverse Diffusion Flame [J]. Acta Chimica Sinica, 2011, 69(08): 1011-1016.
[11]	FANG Yan, DI Guang-Qun, JIANG Bi-Biao, CHEN Jian-Hai. Low-Temperature Atom Transfer Radical Polymerization of Styrene: Diffusion-induced Acceleration [J]. Acta Chimica Sinica, 2011, 69(07): 853-862.
[12]	YANG Jia-Wei, FANG Zheng, PAN Yi, LIU Ren-Hong, WANG Jia-Li, DAN De-Zhong. Study on Effect of Microstructure of Porous Gas Diffusive Electrodes with Different Catalysts for Electrochemical Sensor on Performance of Response for Determination of Formaldehyde [J]. Acta Chimica Sinica, 2011, 69(01): 65-70.
[13]	LIU Jin-Xiang, YOU Long, ZHANG Jun, YAN You-Guo, YU Li-Jun, REN Zhen-Jia. Effect of Temperature on Cysteine Inhibition Efficiency by Mechanism Study and Experiment Evaluation [J]. Acta Chimica Sinica, 2010, 68(18): 1807-1812.
[14]	WANG Jin, WANG Jun-Xia, ZENG Fan-Gui, WU Xiu-Ling. Molecular Simulation of Interlayer Structure and Dynamics Properties in Lithium Montmorillonite Hydrates [J]. Acta Chimica Sinica, 2010, 68(16): 1653-1660.
[15]	YOU Long, LIU Jin-Xiang, ZHANG Jun, LIU Lin-Fa, XU Li-Jun, JIAO Gui-Min. MD Study of Imidazoline Corrosion Inhibition Membranes Restrain Corrosive Medium Diffusion Behaviors [J]. Acta Chimica Sinica, 2010, 68(08): 747-752.

沸石基工业多组元催化剂的结构设计及组元间相互作用研究★

Studies on Structural Engineering and Intercomponent Interactions of Zeolite-Based Industrial Multicomponent Catalysts★

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 12

References 96

Related Articles 15

Recommended Articles

Metrics

Comments

沸石基工业多组元催化剂的结构设计及组元间相互作用研究^★

Studies on Structural Engineering and Intercomponent Interactions of Zeolite-Based Industrial Multicomponent Catalysts^★