Acta Chimica Sinica ›› 1965, Vol. 31 ›› Issue (2): 174-178. Previous Articles     Next Articles

α-甲氧基苯基乙酸与锆的沉淀作用

梁树权, 王顺荣   

  1. 中国科学院化学研究所
  • 投稿日期:1964-05-07 发布日期:2013-06-03

THE PRECIPITATION OF ZIRCONIUM WITH ALPHAMETHOXYPHENYLACETIC ACID

LIANG SHU-CHUAN, WANG SHUN-JUNG   

  1. Institute of Chemistry, Academia Sinica, Peking
  • Received:1964-05-07 Published:2013-06-03

As mandelic acid is known as a specific zirconium precipitant,it is interesting to learn whether its methylated compound,a-methoxyphenylacetic acid,also functions as a zirconium reagent.It is found experimentally that zirconium can be quantitatively thrown down as a basic a-methoxyphenylacetate,in which the mole ratio of zirconium to the reagent is 1:1,from media of pH 0.8-1.4 containing several grams of ammonium chloride.The amount of precipitant added should be about fifteen fold more than the theoretical amount required(calculated on the basis of 1:1).