Acta Chimica Sinica ›› 1982, Vol. 40 ›› Issue (3): 287-288. Previous Articles    

过氧键的圆二色谱

梁晓天   

  1. 中国医学科学院药物研究所 北京
  • 投稿日期:1980-04-07 发布日期:2013-06-03

CIRCULAR DICHROISM OF THE PEROXIDIC LINKAGE

LIANG XIAO-TIAN   

  1. Institute of Materia Medica, Chinese Academy of Medical Sciences, Beijing
  • Received:1980-04-07 Published:2013-06-03

From the CD curves of compounds 1-3(Fig. 1 in Chinese Text;compound 4 being transparent),it is seen that the positive absorption drift of 1 and 3 may be attributed to the peroxidic linkage, which is twisted clockwise as shown by molecular models. However, more eganiples will be needed to vindicate the proposed correspondence between the handedness of the torsion angle of the perogidic linkage and the sign of tho CD background.