Studies on the organosilicon reactive intermediates I: Generation of furylphenylsilylene by photochemical method

Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (11): 1107-1111. Previous Articles Next Articles

Original Articles

有机硅反应活性中间体的研究I:光化学方法产生含呋喃环硅烯

吴世晖;武戈;陶凤岗;林子森

复旦大学化学系

发布日期:1987-11-15

Studies on the organosilicon reactive intermediates I: Generation of furylphenylsilylene by photochemical method

WU SHIHUI;WU GE;TAO FENGGANG;LIN ZISEN

Published:1987-11-15

Abstract

a-Furylphenylsilylene was generated by the photolysis of 2-(a-furyl)-2-phenylhexamethyltrisilane. When a a-furylphenylsilylene reacted with 2,3-dimethyl-1,3-butadiene, the expected addition and insertion reaction products I and II were obtained. The intermediate silirane derivative resulted from the reaction of a-furylphenylsilylene with cyclohexene was decomposed by methanol to give a-furylphenylcyclohexylmethoxysilane.

Key words: PHOTOCHEMICAL REACTION, BENZENE P, CYCLOHEXANE P, FURAN P, FURAN P, ORGANO SILICON COMPOUNDS, SILANE P, CYCLOHEXENE, BUTADIENE P, SILYLENE

CLC Number:

O627

Cite this article

WU SHIHUI;WU GE;TAO FENGGANG;LIN ZISEN. Studies on the organosilicon reactive intermediates I: Generation of furylphenylsilylene by photochemical method[J]. Acta Chimica Sinica, 1987, 45(11): 1107-1111.

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有机硅反应活性中间体的研究I:光化学方法产生含呋喃环硅烯

Studies on the organosilicon reactive intermediates I: Generation of furylphenylsilylene by photochemical method

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