Study on the mechanism of photolysis of O-acyl-α-oximinoketone

Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (10): 984-989. Previous Articles Next Articles

Original Articles

O-酰基-α-酮肟光分解机理的研究

童伟达;杨玉良;孙猛;于同隐

复旦大学材料科学系

发布日期:1989-10-15

Study on the mechanism of photolysis of O-acyl-α-oximinoketone

TONG WEIDA;YANG YULIANG;SUN MENG;YU TONGYIN

Published:1989-10-15

Abstract

The title mechanism was studied by IR spectroscopy. Kinetic equations of this photodecompn. were simulated to give the apparent kinetic parameters. N-O bond cleavage and the Norrish-type reaction proceed simultaneously, and the fraction of N-O bond cleavage depends on the substituents.

Key words: INFRARED SPECTROPHOTOMETRY, OXIME, KINETICS EQUATIONS, CHEMICAL BONDS, REACTION RATE CONSTANT, PHOTODECOMPOSITION, ACYL GROUP, KETONE P

CLC Number:

O621.16
O644

Cite this article

TONG WEIDA;YANG YULIANG;SUN MENG;YU TONGYIN. Study on the mechanism of photolysis of O-acyl-α-oximinoketone[J]. Acta Chimica Sinica, 1989, 47(10): 984-989.

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O-酰基-α-酮肟光分解机理的研究

Study on the mechanism of photolysis of O-acyl-α-oximinoketone

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