Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (10): 990-995. Previous Articles     Next Articles

Original Articles

芳香族羟肟的合成及其萃取铜的结构-性能研究

袁承业;向才立;李树林;蒋锡琪;王娇;潘柏熙;曹炽明   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1989-10-15

Synthesis of aromatic hydroxyoximes and their structure-reactivity studies in copper extraction

YUAN CHENGYE;XIANG CAILI;LI SHULIN;JIANG XIQI;WANG JIAO;PAN BAIXI;CAO ZHIMING   

  • Published:1989-10-15

The charge d. of phenolic oxygen and oximido nitrogen obtained by the HMO method plays an important role in copper extration by the title compounds The relation between chem. structure and extration properties was evaluated; pKa was not important with the 15 title compounds prepared The structural effect was rationalized by the formation of the stable square planar coordination compound

Key words: STRUCTURE PARAMETER, AROMATIC HYDROCARBON, COPPER, TRANSFORM, EXTRACTION, EQUILIBRIUM CONSTANT, OXIME, REGRESSION ANALYSIS, STRUCTURE AND PROPERTY CORRELATION, MOLECULAR ORBITAL THEORY

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