Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (11): 1105-1108. Previous Articles     Next Articles

Original Articles

过渡金属卡宾配合物:VIII. 四羰基[乙氧基(芳基)卡宾]铁配合物的方便合成法

陈家碧;雷桂馨;殷建国   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1989-11-15

Transition metal carbene complexes:VII. A convenient synthesis of tetracarbonyl ethoxy(aryl)carbene iron complexes

CHEN JIABI;LEI GUIXIN;YIN JIANGUO   

  • Published:1989-11-15

Six title complexes, (CO)4FeC(OC2H5)Ar (Ar: C6H5, o-CH3C6H4, p-CH3C6H4, p-CH3OC6H4, C6Cl5, p-CF3C6H4) have been prepared by reaction of Fe(CO)5 with ArLi in ether at low temperature followed by alkylation of the acylmetalate intermediates formed with Et3OBF4 in aqueous solution at 0?

Key words: ETHOXY GROUP, IRON COMPLEX, CARBONYL COMPLEX, CARBENE, TRANSITION METAL COMPLEX

CLC Number: