Study on platinum hydrides II: Syntheses and identifications of new platinum hydrides PtH(PPh3)(S2CNR2^1) and trans-PtH(PCy)32(S2CNR2^1)

Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (2): 191-193. Previous Articles Next Articles

Original Articles

铂氢化物的研究 II: 新铂氢化物PtH(PPh3)(S2CNR2^1)及trans-PtH(PCy3)2(S2CNR2^1)的合成与结构鉴定

魏春红;贝浼智;郭和夫

中国科学院大连化学物理研究所

发布日期:1989-02-15

Study on platinum hydrides II: Syntheses and identifications of new platinum hydrides PtH(PPh3)(S2CNR2^1) and trans-PtH(PCy)32(S2CNR2^1)

WEI CHUNHONG;BEI MEIZHI;GUO HEFU

Published:1989-02-15

Abstract

trans-PtHCl(PPh3)2 and trans-PtHCl(PCy3)2 (Cy = cyclohexyl) reacted with NaS2CNR2 (R = Et, Bu, CH2Ph) to give PtH(PPh3)(S2CNR2) (I) and trans-PtH(PCy3)2(S2CNR2), resp. The complexes were characterized by IR and 1H and 31P NMR spectra and TGA. I (R = Et) reacted with CCl4 to give CHCl3.

Key words: INFRARED SPECTROPHOTOMETRY, GAS CHROMATOGRAPHY, ELEMENTAL ANALYSIS, NMR SPECTROMETRY, CYCLOHEXANE P, STRUCTURAL ANALYSIS, PLATINUM COMPLEX, TRIPHENYLPHOSPHINE, HYDRIDES, THERMOGRAVIMETRY

CLC Number:

O627

Cite this article

WEI CHUNHONG;BEI MEIZHI;GUO HEFU. Study on platinum hydrides II: Syntheses and identifications of new platinum hydrides PtH(PPh3)(S2CNR2^1) and trans-PtH(PCy)32(S2CNR2^1)[J]. Acta Chimica Sinica, 1989, 47(2): 191-193.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Li Xiaoxin, Shu Lun, Chen Sha. Application of Metal-Organic Frameworks in Chromatographic Separation [J]. Acta Chim. Sinica, 2016, 74(12): 969-979.
[2]	Mei Zhen, Cai Wensheng, Shao Xueguang. Rapid Analysis of Pesticide Mixture by Gas Chromatography-Mass Spectrometry with a New Alternative Iterative Algorithm [J]. Acta Chimica Sinica, 2013, 71(05): 729-732.
[3]	Yang Dawei, Fan Xiaolei, Kind Tobias, Fiehn Oliver, Guo Rongbo. Analysis of Polar Lipids in Chlamydomonas reinhardtii Using Nanoelectrospray Direct Infusion Method and Gas Chromatography and Mass Spectrometric Detection [J]. Acta Chimica Sinica, 2013, 71(04): 663-669.
[4]	Qi Suitao, Huang Jun, Chen Hao, Gao Zifeng, Yi Chunhai, Yang Bolun. Development of Dehydrogenation Catalyst for Reversible Hydrogen Storage in Organic Hydrides [J]. Acta Chimica Sinica, 2012, 70(24): 2467-2474.
[5]	Li Ming, Li Zaijun, Li Guanyan, Chen Linjie, Wang Lina, Jiang Cuicui, Li Lulu, Zhang Zhuangtai. Symmetrical 1,3-Dialkylimidazolium Ionic Liquid Based Single-Drop Microextraction Coupled to GC-MS for the Determination of Esters in Natural Flavors [J]. Acta Chimica Sinica, 2012, 70(15): 1625-1630.
[6]	Fu Xiaowei, Ni Zheming, Liu Jiao. Surface Characterization of Copper-Aluminum-Magnesium Hydrotalcites Investigated by Inverse Gas Chromatography [J]. Acta Chimica Sinica, 2012, 70(08): 968-972.
[7]	Jia Fengyan, Wang Wenwen, Liu Zhenbo, Yin Jungang, Liu Yongming. Extraction and Detection of Pyrethroids Pesticides in Fish Using Acetonitrile-Salt-H₂O System Coupled with Gas Chromatography [J]. Acta Chimica Sinica, 2012, 0(04): 485-491.
[8]	Liu Huijun, Chen Shuang, Wang Peng, Lu Lu, Pan Zaifa, Wang Lili. Flash Evaporation-Gas Chromatography Determination with Pattern Recognition Analysis for Curcuma zedoaria Rosc. [J]. Acta Chimica Sinica, 2012, 70(01): 78-82.
[9]	WANG Xue-Rong, LIU Zhen-Bo, JIA Feng-Yan, ZHANG Qiang, YIN Jun-Gang, LIU Yong-Ming. Study on the Form of Organic Phosphorus in Aquatic Products and Its Analytical Application [J]. Acta Chimica Sinica, 2011, 69(20): 2505-2510.
[10]	. Thermal Decomposition Mechanism and Kinetics of N-(phenylacetamido)-N’-(α-naphthylaceto) Thiourea [J]. Acta Chimica Sinica, 2009, 67(8): 838-842.
[11]	. Quantitative Structure-Retention Relationship for Terpenes and Their Application in Structure Characterization [J]. Acta Chimica Sinica, 2009, 67(4): 289-294.
[12]	ZHANG Bin-Ban, JIU Cun-Qian, CUI Jian-Jie. Comparative Analysis of Volatile oils form Lotus Leaves by Purge and Trap-Thermal Desorption Gas Chromatography-Mass Spectrometry [J]. Acta Chimica Sinica, 2009, 67(20): 2368-2374.
[13]	CHEN, Jun-Rong XU, Bu-Yi CAI, Jing LI, Quan* LUO, Kai-Jun ZHAO, Ke-Qing . Theoretical Studies on Electronic Spectra and Second-order Nonlinear Optical Properties of Cyclometalated Platinum Complexes with Long Chain β-Diketonate Ancillary Ligands [J]. Acta Chimica Sinica, 2008, 66(13): 1513-1517.
[14]	LIU Xiao-Hua; WU Zong-Bin²; ZHANG Ping^,1; TANG Zhi-Yong; ZHU Hua-Ping; DUAN Shi-Jie²; MAO Zong-Qiang^,2. Monitoring Reactive Degree of Biodiesel Catalyzed by Calcium Oxide via Gas Chromatography [J]. Acta Chimica Sinica, 2007, 65(18): 2025-2028.
[15]	LI Lai-Sheng*; WANG Shang-Wen; LIU Chao; XU Li-Li. Preparation of Glycoluril and Perhydroxycucurbit[6]uril GC Stationary Phase and Comparative Studies on Their Separation Performances [J]. Acta Chimica Sinica, 2007, 65(17): 1855-1862.

铂氢化物的研究 II: 新铂氢化物PtH(PPh3)(S2CNR2^1)及trans-PtH(PCy3)2(S2CNR2^1)的合成与结构鉴定

Study on platinum hydrides II: Syntheses and identifications of new platinum hydrides PtH(PPh3)(S2CNR2^1) and trans-PtH(PCy)32(S2CNR2^1)

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments