Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (2): 204-208. Previous Articles    

Original Articles

过渡金属三乙酰基丙酮配合物与 吨酮三重态之间的电子能量转移作用

沈玉全;曹怡;刘蕙平;喻长军;刘新厚   

  1. 中国科学院感光化学研究所
  • 发布日期:1989-02-15

The interaction of electronic energy transfer between trisacetylacetonato transition metal complexes and triplex excited state of xanthone

SHEN YUQUAN;CAO YI;LIU HUIPING;YU CHANGJUN;LIU XINHOU   

  • Published:1989-02-15

Processes) By using the quenching reaction of a-pinene photoisomerization sensitized by xanthone, the quenching reactivity of transition metal complexes of acetylacetonate was determine The rate constants obtained were interpreted based on the Dexter theory, and experimental evidence for the electronic energy transfer mechanism of the process is presented.

Key words: PHOTOCHEMISTRY, IRON COMPLEX, XANTHENONE, PENTANEDIONE P, TRANSITION METAL COMPLEX, ISOMERIZATION REACTION, SENSITIZATION, ENERGY TRANSFER, PINENE, TRIPLET

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