Studies on olefin-coordinating transition metal carbene complexes: XVI, an unusual ring-opening reaction of tetrafluorobenzobicyclo chelated diallyl dicarbonyliron complexes

Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (2): 195-203. Previous Articles Next Articles

Original Articles

烯烃配位的过渡金属卡宾配合物的研究XVI:四氟苯并双环[2,2,2]辛三烯三羰基铁的新奇开环反应-新型螯合双烯丙基三羰基铁配合物的合成和结构

陈家碧;殷建国;徐维;来鲁华;张泽莹;邵美成

中国科学院上海有机化学研究所;北京大学物理化学研究所

发布日期:1990-02-15

Studies on olefin-coordinating transition metal carbene complexes: XVI, an unusual ring-opening reaction of tetrafluorobenzobicyclo chelated diallyl dicarbonyliron complexes

CHEN JIABI;YIN JIANGUO;XU WEI;LAI LUHUA;ZHANG ZEYING;SHAO MEICHENG

Published:1990-02-15

Abstract

Reaction of the title compound with ArLi (Ar = Ph; o-, m-, p-tolyl; p-MeOC6H4; p-ClC6H4) in ether at low temps., and subsequent alkylation of the formed acylmetalates with Et3OBF4 in aqueous solution at 0?led to the novel ring-opening reaction of the bicyclodiene ligand to give the chelated diallyl dicarbonyliron complexes of composition (C12H6F4)(CO)2FeC(OC2H5)Ar. The structure of one complex was determine by x-ray crystallog.

Key words: BENZENE P, IRON COMPLEX, CARBONYL COMPLEX, CARBENE, LITHIUM COMPOUNDS, CARBONYL COMPOUNDS, IRON COMPOUNDS, RING CLEAVAGE REACTION, FLUOROHYDROCARBON, TRANSITION METAL COMPLEX

CLC Number:

O611.662

Cite this article

CHEN JIABI;YIN JIANGUO;XU WEI;LAI LUHUA;ZHANG ZEYING;SHAO MEICHENG. Studies on olefin-coordinating transition metal carbene complexes: XVI, an unusual ring-opening reaction of tetrafluorobenzobicyclo chelated diallyl dicarbonyliron complexes[J]. Acta Chimica Sinica, 1990, 48(2): 195-203.

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烯烃配位的过渡金属卡宾配合物的研究XVI:四氟苯并双环[2,2,2]辛三烯三羰基铁的新奇开环反应-新型螯合双烯丙基三羰基铁配合物的合成和结构

Studies on olefin-coordinating transition metal carbene complexes: XVI, an unusual ring-opening reaction of tetrafluorobenzobicyclo chelated diallyl dicarbonyliron complexes

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