Syntheses and structure analysis of bulkier substituted cyclopentadienyl carbonyl moly bdenum compounds

Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (7): 720-726. Previous Articles

Original Articles

大取代茂钼化合物的合成与结构分析

王家喜;陈寿山;王序昆;王宏根

南开大学中心实验室;南开大学元素有机化学研究所

发布日期:1993-07-15

Syntheses and structure analysis of bulkier substituted cyclopentadienyl carbonyl moly bdenum compounds

WANG JIAXI;CHEN SHOUSHAN;WANG XUKUN;WANG HONGGEN

Published:1993-07-15

Abstract

Thirteen molybdenum-molybdenum dimetallic and five molybdenum-halide cyclopentadienyl carbonyl compounds have been prepared from complexed hexacarbonylmolybdenum with bulkier substituted cyclopentadienyl anions which came from the reaction of 6,6-dialkylfulvenes with aryllithium. Their IR, 1H NMR, 95Mo NMR spectra have been discussed. The crystal structure of [(CH3)2C(m-CH3C6H4)C5H4]Mo(CO)3Br was determine

Key words: INFRARED SPECTROPHOTOMETRY, CRYSTAL STRUCTURE, BENZENE P, CYCLOPENTADIENE P, BROMIDE, PROTON MAGNETIC RESONANCE SPECTROMETRY, MOLYBDENUM COMPLEX, CARBONYL COMPOUNDS, METALLOCENES, ORGANO LITHIUM COMPOUNDS

CLC Number:

O627

Cite this article

WANG JIAXI;CHEN SHOUSHAN;WANG XUKUN;WANG HONGGEN. Syntheses and structure analysis of bulkier substituted cyclopentadienyl carbonyl moly bdenum compounds[J]. Acta Chimica Sinica, 1993, 51(7): 720-726.

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大取代茂钼化合物的合成与结构分析

Syntheses and structure analysis of bulkier substituted cyclopentadienyl carbonyl moly bdenum compounds

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