Studies on a new effect of fluorescent sensitization based on the formation of heteropolynuclear complex.Ⅰ.fluorescent properties of the ternary system Mn(Ⅱ)-7-(8-hydroxy-3,6-disulfonaphthylazo)-8-hydroxyquinoline -5-sulfonic acid-b(Ⅲ)and their analyti

Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (9): 897-902. Previous Articles Next Articles

Original Articles

一种基于形成杂多核配合物的荧光增敏效应的研究Ⅰ.锰(Ⅱ)-7-(8-羟基-3,6-二磺基萘偶氮)-8-羟基喹啉-5-磺酸-硼(Ⅲ)三元体系的荧光性质及其分析应用

熊国华;黄坚锋;俞英;刘虹;严中一

江西九江师范专科学校化学系;江西大学中心实验室

发布日期:1993-09-15

Studies on a new effect of fluorescent sensitization based on the formation of heteropolynuclear complex.Ⅰ.fluorescent properties of the ternary system Mn(Ⅱ)-7-(8-hydroxy-3,6-disulfonaphthylazo)-8-hydroxyquinoline -5-sulfonic acid-b(Ⅲ)and their analyti

XIONG GUOHUA;HUANG JIANFENG;YU YING;LIU HONG;YAN ZHONGYI

Published:1993-09-15

Abstract

When Mn(II) is added into 7-(8-hydroxy-3,6-disulfonaphthylazo)-8-hydroxyquinoline-5-sulfonic acid-boron(III) fluorescence system at nonequil. condition, the fluorescence intensity is greatly increased. It is confirmed that the sensitivity enhancement effect is due to the formation of heteronuclear complex, B-Mn-reagent. A sensitive fluorescence method is hereby established for Mn determination The linear range and detection limit of the method are 0-2.9 x 10-7 and 3 x 10-9 mol Mn/L, resp. The method was applied to the determination of Mn in synthetic samples and foods.

Key words: FLUORIMETRIC ANALYSIS, TERNARY SYSTEM, NAPHTHALENE P, BENZENE AZO COMPOUNDS, GRAIN, BORON COMPLEX, POLYNUCLEAR COMPLEX, MANGANESE COMPLEX, HYDROXY QUINOLINES, SULFONIC ACID P

CLC Number:

Cite this article

XIONG GUOHUA;HUANG JIANFENG;YU YING;LIU HONG;YAN ZHONGYI. Studies on a new effect of fluorescent sensitization based on the formation of heteropolynuclear complex.Ⅰ.fluorescent properties of the ternary system Mn(Ⅱ)-7-(8-hydroxy-3,6-disulfonaphthylazo)-8-hydroxyquinoline -5-sulfonic acid-b(Ⅲ)and their analyti[J]. Acta Chimica Sinica, 1993, 51(9): 897-902.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Fei Li, Huili Ding, Chaozhong Li. Hydrotrifluoromethylation of Alkenes with a Fluoroform-Derived Trifluoromethylboron Complex [J]. Acta Chimica Sinica, 2023, 81(6): 577-581.
[2]	Quan Xuebo, Dong Jiaqi, Zhou Jian. Effect of Topology of Hydrophobic Surfaces on Their Wetting States by Coarse-grained Simulations [J]. Acta Chimica Sinica, 2014, 72(10): 1075-1078.
[3]	Luo Jian, Wang Yi, Jiang Jibo, Zhong Qingdong, Zhu Zhenyu, Zhang Lei. Electrochemistry Behavior of Rebars with Different Grain Size and Mott-Schottky Research of Passive Films [J]. Acta Chimica Sinica, 2012, 70(10): 1213-1220.
[4]	ZHANG Hong-Yu, WANG Yan-Yan, TAO Guo-Qiang, GUI Bin, YIN Chang-Long, CHAI Yong-Ming, QUE Guo-He. Coarse Grained Molecular Mechanics (MM)/Molecular Dynamics (MD) Force Field for Petroleum Chemistry: I. Coarse Grained Model for Alkanes in Petroleum [J]. Acta Chimica Sinica, 2011, 69(17): 2053-2062.
[5]	YU Hui, LI Zhuo, ZHAO Xi, HUANG Xu-Ri. Multi-scale Molecular Simulations Study on the Gating Mechanism in a Pentameric Ligand-gated Ion Channel from Gloebacter Violaceus [J]. Acta Chimica Sinica, 2011, 69(14): 1639-1644.
[6]	. Preparation and Phase Transformation of (Li0.06Na0.47K0.47)NbO3 Nano-powders Derived from Sol-gel Process [J]. Acta Chimica Sinica, 2009, 67(3): 203-207.
[7]	ZHOU De-Feng*^,1; GUO Wei; ZHU Jian-Xin; HAO Xian-Feng²; GE Zhi-Min; YE Jun-Feng; MENG Jian². Effects of Pr Dopant on Grain Boundary and Electrical Properties of Ce_5.2Sm_0.8MoO_15－δ [J]. Acta Chimica Sinica, 2007, 65(14): 1313-1317.
[8]	LI Zhi, ZHENG Tong, PENG Bi-Xian, CHEN Li-Juan*. Light Absorption Properties of Monodispersed Micron/Nano-sized Silver Halide Emulsions: Cubic Silver Halide and AgCl {100} T-grain [J]. Acta Chimica Sinica, 2006, 64(9): 833-838.
[9]	LIU Gui-Li*; LI Rong-De; GUO Yu-Fu. Electronic Theory Study on the Influence of Rare Earth Elements on the Intergranular Corrosion of ZA27 Alloys [J]. Acta Chimica Sinica, 2006, 64(16): 1631-1634.
[10]	SHAO Guang-Jie^1,2; QIN Xiu-Juan*^,1,2; LIU Ri-Ping; WANG Wen-Kui^1,3. Grain Evolution Dynamics of ZnO Nanocrystals under High Pressure and Temperature [J]. Acta Chimica Sinica, 2006, 64(16): 1649-1653.
[11]	DUAN Yu-Ping*,LIU Shun-Hua,GUAN Hong-Tao,WEN Bin. Effects of High Magnetic Field on Grain Shape and Electrical Conductivity of Doped Polyaniline [J]. Acta Chimica Sinica, 2005, 63(17): 1595-1599.
[12]	REN Yan-Wei, LI Jun*, WU Ai-Zhi, LI Shu-Ni, ZHANG Feng-Xing. Synthesis, Structure and Properties of Mixed-Valence Tetranuclear Manganese Complex [Mn₄O₂(ClCH₂COO)₇(bipy)₂]•H₂O [J]. Acta Chimica Sinica, 2005, 63(10): 919-923.
[13]	YUAN Ai-Hua, WANG Ping, LI Kui, YANG Xu-Jie, WANG Xin, LU Lu-De, YU Kai-Bei. Synthesis, Crystal Structure and Magnetic Properties of a New Three-dimensional Cyanide-bridged Coordination Polymer,{[Ni(tn)][Ni(CN)₄]·2H₂O}_n [J]. Acta Chimica Sinica, 2004, 62(11): 1029-1033.
[14]	Zhang Qizhen;Sheng Xin;Yin Xiaoying;Ji Yiping;Li Guang;Zhao Xiaoguang. Study on a Carbosilane Liquid Crystalline Dendrimer of the First Generation-Containing Twelve 4-Nitroazobenzene Mesogen in Its Periphery [J]. Acta Chimica Sinica, 2003, 61(9): 1478-1483.
[15]	Sun Min;Xin Hao;Zhang Yongan;Wang Kezhi;Jin Linpei;Huang Chunhui. Synthesis, Characterization and Photoelectric Properties of a Novel Carbazole-containing Re(Ⅰ)Complex [J]. Acta Chimica Sinica, 2003, 61(8): 1323-1325.

一种基于形成杂多核配合物的荧光增敏效应的研究Ⅰ.锰(Ⅱ)-7-(8-羟基-3,6-二磺基萘偶氮)-8-羟基喹啉-5-磺酸-硼(Ⅲ)三元体系的荧光性质及其分析应用

Studies on a new effect of fluorescent sensitization based on the formation of heteropolynuclear complex.Ⅰ.fluorescent properties of the ternary system Mn(Ⅱ)-7-(8-hydroxy-3,6-disulfonaphthylazo)-8-hydroxyquinoline -5-sulfonic acid-b(Ⅲ)and their analyti

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments