Surface analysis for the hydrogen storage alloy and electrocatalytic activity of MH electrodes

Acta Chimica Sinica ›› 1998, Vol. 56 ›› Issue (6): 564-569. Previous Articles Next Articles

Original Articles

贮氢合金表面分析和金属氢化物电极电催化活性

陈卫祥;唐致远;陈长聘

浙江大学材料科学与工程学系;天津大学应用化学系

发布日期:1998-06-15

Surface analysis for the hydrogen storage alloy and electrocatalytic activity of MH electrodes

CHEN WEIXIANG;TANG ZHIYUAN;CHEN CHANGPING

Published:1998-06-15

Abstract

The morphology and surface composition of the hydrogen storage alloy are important factors that affect the performances of metal hydride (MH) electrodes. The performances of MH eelctrodes are effectively improved by the surface modification. The morphology and composition of the treated alloys were analyzed by XPS, ICP and BET. The effect of the chemical reducingtreatment on the electrocatalytic activity of MH electrodes was discussed. It was found that the exchange current density of MH electrode increased markedly and the activation energy of electrode reaction decreased.

Key words: HYDRIDES, ACTIVATION ENERGY, ELECTRO-CATALYSIS, ELECTRODE REACTION, CATALYTIC BEHAVIOUR, ADJUSTER

CLC Number:

O646

Cite this article

CHEN WEIXIANG;TANG ZHIYUAN;CHEN CHANGPING. Surface analysis for the hydrogen storage alloy and electrocatalytic activity of MH electrodes[J]. Acta Chimica Sinica, 1998, 56(6): 564-569.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Wang Yinghui, Jie Jialong, Zhao Hongmei, Bai Yu, Qin Peixuan, Song Di. Deprotonation of Guanine Radical Cation in G-Quadruplex: A Combined Experimental and Theoretical Study [J]. Acta Chim. Sinica, 2018, 76(6): 475-482.
[2]	Chen Fangfang, Sun Xiaohui, Yao Qian, Li Zerong, Wang Jingbo, Li Xiangyuan. Accurate Calculation of the Energy Barriers and Rate Constants of the Large-size Molecular Reaction System for Abstraction from Alkyl Hydroperoxides [J]. Acta Chim. Sinica, 2018, 76(4): 311-318.
[3]	Wu Lidan, Jie Jialong, Liu Kunhui, Su Hongmei. Deprotonation Kinetics of 1-Methylguanine After One-Electron Oxidation [J]. Acta Chimica Sinica, 2014, 72(11): 1182-1186.
[4]	Wei Xiaoping, Chang Chuan, Li Jianping. A Molecular Imprinted Electrochemical Sensor For Selectively and Electro-catalytically Voltammetric Determination of Dopamine [J]. Acta Chimica Sinica, 2013, 71(06): 951-956.
[5]	Qi Suitao, Huang Jun, Chen Hao, Gao Zifeng, Yi Chunhai, Yang Bolun. Development of Dehydrogenation Catalyst for Reversible Hydrogen Storage in Organic Hydrides [J]. Acta Chimica Sinica, 2012, 70(24): 2467-2474.
[6]	YANG Guo-Hui, LI Yan-Xin, YAN Shi-Hai, DAI Li, ZHAO Bin. Theoretical Study on Proton Transfer of 2-[(4-Chlorophenylimino)- methyl]-8-hydroxyquinoline [J]. Acta Chimica Sinica, 2011, 69(15): 1743-1750.
[7]	. Semi-aromatic Copolyamide: Synthesis and Thermal Stability [J]. Acta Chimica Sinica, 2009, 67(9): 983-988.
[8]	. Theoretical Study of Reaction Mechanism of Silylene with Isothiocyanic Acid [J]. Acta Chimica Sinica, 2009, 67(8): 773-780.
[9]	. Synthesis and Thermal Decomposition Kinetics of Novel Flame Retardant 1,3,5-Tris(5,5-dimethyl-1,3-dioxa-2- oxophosphorinanyl-2-oxy)benzene [J]. Acta Chimica Sinica, 2009, 67(14): 1695-1699.
[10]	LAI Yuan* ZHOU De-Bi HU Jian-Wen CUI Li-Li. Electrochemical Performance of Co-N/C Complex Catalyst for Alkaline Fuel Cell [J]. Acta Chimica Sinica, 2008, 66(9): 1015-1020.
[11]	REN Yuan-Lin*¹² CHENG Bo-Wen² ZHANG Jin-Shu² KANG Wei-Min¹² LI Zhen-Huan² ZHUANG Xu-Pin^{12. Study on Thermal Decomposition Kinetics of N,N′-Bis(5,5-dimethyl- 2-phospha-2-thio-1,3-dioxan-2-yl)ethylenediamine in Air [J]. Acta Chimica Sinica, 2008, 66(9): 1123-1128.}
[12]	WANG Wen-Liang*^,1; REN Hong-Jiang^1,2; WANG Wei-Na. DFT Theoretical Study on the Proton Transfer Isomerization of 2,6-Dithiopurine [J]. Acta Chimica Sinica, 2007, 65(3): 207-214.
[13]	GENG Zhi-Yuan*; HAN Yan-Xia; WANG Yong-Cheng; LIANG Jun-Xi; YAN Pen-Ji; YAO Kun; JIA Bao-Li. Theoretical Study of the Reaction Mechanism for SiH₂ Radical with HNCO [J]. Acta Chimica Sinica, 2007, 65(24): 2839-2846.
[14]	PENG Bao-Zi; LUO Hu; SUN Chang-Yu; MA Qing-Lan; ZHOU Wei; CHEN Guang-Jin*. Study on Growth Kinetics of Methane Hydrate Film [J]. Acta Chimica Sinica, 2007, 65(2): 95-99.
[15]	REN Yuan-Lin*; CHENG Bo-Wen; ZHANG Jin-Shu. Study on Thermal Decomposition Kinetics of N,N'-Bis- (5,5-dimethyl-2-phospha-2-thio-1,3-dioxan-2-yl) ethylene diamine [J]. Acta Chimica Sinica, 2007, 65(17): 1892-1896.

贮氢合金表面分析和金属氢化物电极电催化活性

Surface analysis for the hydrogen storage alloy and electrocatalytic activity of MH electrodes

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments