Acta Chimica Sinica ›› 1998, Vol. 56 ›› Issue (7): 714-718. Previous Articles     Next Articles

Original Articles

NaBH4/BiCl3复合体系还原芳香硝基化合物为氧化偶氮苯及其类似物

任平达;潘士峰;董庭威;吴世晖   

  1. 复旦大学化学系
  • 发布日期:1998-07-15

Reduction of aromatic nitro compounds to azoxy compounds with NaBH4/BiCl3 system

Ren Pingda;PAN SHIFENG;DONG TINGWEI;WU SHIHUI   

  • Published:1998-07-15

Nitroarenes could be conveniently reduced to the corresponding azoxybenzenes by NaBH4/BiCl3 system in methanol. The results of this reaction depended largely on the Hammett's constants of the reactants.

Key words: INFRARED SPECTROPHOTOMETRY, NMR SPECTROMETRY, NITROBENZENE P, BENZENE AZO COMPOUNDS, SODIUM BOROHYDRIDE, BISMUTH CHLORIDE

CLC Number: