Acta Chimica Sinica ›› 1999, Vol. 57 ›› Issue (5): 453-457. Previous Articles     Next Articles

Original Articles

低能氮离子对苯甲酸钠溶液的化学改性

韩建伟;王相勤;余增亮   

  1. 中国科学院等离子体物理研究所.合肥(230031)
  • 发布日期:1999-05-15

Chemical modification of PhCOONa solution by low-energy nitrogen ions

Han Jianwei;Wang Xiangqin;Yu Zengliang   

  1. Inst of Plasma Phys, CAS.Hefei(230031)
  • Published:1999-05-15

Low-energy nitrogen ions were produced with gas point discharge, and the ions were accelerated directly by the potential degradation above the cathode into PhCOONa solution. The induced change for UV absorption was measured. After the nitrogen ions impact, PhCOONa solution showed positive reaction with ninhydrin, which indicated that some types of amino group were formed when the nitrogen ions attack the solution. The investigation of infrared spectra further demonstrated that amide and nitroso-compound were the damage products. In general, the present paper clearly demonstrates the chemical modification effects of low energy ions on substances in solution.

Key words: BENZENECARBOXYLIC ACID P, CHEMICAL MODIFICATION, NITROGEN ION, NINHYDRIN, INFRARED SPECTROPHOTOMETRY

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