Electrochemical copolymerization of 3-methylthiophene  and 3- chlorothiophene

Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (10): 1818-1822. Previous Articles Next Articles

Original Articles

3-甲基噻吩和3-氯噻吩的电化学共聚

石高全;张家鑫;陈凤恩;徐景坤;洪啸吟

清华大学化学系.北京(100084)

发布日期:2001-10-15

Electrochemical copolymerization of 3-methylthiophene and 3- chlorothiophene

Shi Gaoquan;Zhang Jiaxin;Chen Fengen;Xu Jingkun;Hong Xiaoyin

Tsing Hua Univ, Dept Chem.Beijing(100084)

Published:2001-10-15

Abstract

3-methylthiophene and 3-chlorothiophene have been electrochemically copolymerized in boron-triflTHIOPHE diethyl etherate solution. The formation of copolymer has been confirmed by voltammetry, FT-IR and Raman spectroscopies. Experimental results showed that the new copolymer had higher capacity for charging than that of poly(3- methylthiophene)(PMTh) or poly (3-chlorothiophene)(PCTh). The initial monomer ratio affects strongly on the structure andelectrochemical behavior of the copolymer.

Key words: THIOPHENE P, ELECTROCHEMISTRY, COPOLYMERIZATION, INFRARED SPECTROPHOTOMETRY, RAMAN SPECTROMETRY

CLC Number:

O646

Cite this article

Shi Gaoquan;Zhang Jiaxin;Chen Fengen;Xu Jingkun;Hong Xiaoyin. Electrochemical copolymerization of 3-methylthiophene and 3- chlorothiophene[J]. Acta Chimica Sinica, 2001, 59(10): 1818-1822.

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3-甲基噻吩和3-氯噻吩的电化学共聚

Electrochemical copolymerization of 3-methylthiophene and 3- chlorothiophene

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