The electronic structures of Keggin-type heteropolyanions (XMo12O40) ^-(X=B, Al, Si, Ge, P, As, S) have been calculated by the Density Functional Theory coupled with Discrete Variational Method(DFT-DVM). Based on the calculated results of the seven heteropolym anions, we discussed the influence of the central atoms on the electronic structure, stability, oxidizability and acidity. These results give the sequences of (1) stability, (2) acidity and (3) oxidizability of seven heteropoly anions respectively, as follows: (1) (SMo12O40)^2-> (AsMo12O40)^3>(PMo12O40)^3- (GeMo12O40)^4(BMo12O40)^5-(SiMo12O40)^4 (AlMo12O40)^5-; (2) H2SMo12O40>H3AsMO12O40>H3PMo12O40> H4 GeMo12O40>H4 SiO12O40>H5 AlMo12O40>H5BMo12O40; (3)(SMo12O40)^2-> (AsMo12O40)^3->(PMo12O40)^3-> (GeMo12O40)^4->(SiMo12O4)^4->(AlMo12O40) ^5-> (BMo12O40)^5-. These sequences are strongly supported by many experimental results.

Key words: ELECTRONIC STRUCTURE, STABILITY, HETEROPOLYACID