Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (8): 1340-1343. Previous Articles     Next Articles

Original Articles

芳基取代的手性恶唑啉铝氢化物的制备及其对酮羰 基的不对称还原反应

吴海臣;徐东成;花文廷   

  1. 北京大学化学学院
  • 发布日期:2001-08-15

The synthesis of novel chiral aryloxzoline hydroaluminum and its asymmetric reduction for ketones

Wu Haichen;Xu Dongcheng;Hua Wenting   

  • Published:2001-08-15

o-Hydroxybenzyloxazolines as chiral ligand have been synthesized. A new type of bis (aryloxazoline)-modified lithium aluminum hydride reducing agent (DIOAL-H) was prepared, which exhibits moderate enantioselectivity in the reduction of different ketones.

Key words: CHIRAL REAGENT, KETONE, REDUCTION REACTION, OXAZOLINE, ALUMINIUM COMPLEX

CLC Number: