Atom Transfer Radical Polymerization of Styrene and Methyl Methacrylate Initiated by 5-Norborn-2-enyl Methyl Chloroacetate

Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (8): 1485-1489. Previous Articles Next Articles

Original Articles

梳型接枝共聚物的合成（IV）-氯乙酸降冰片烯甲酯引发苯乙烯、甲基丙烯酸甲酯原子转移自由基聚合的研究

李永胜;李弘;何炳林

南开大学高分子化学研究所.天津(300071)

发布日期:2002-08-15

Atom Transfer Radical Polymerization of Styrene and Methyl Methacrylate Initiated by 5-Norborn-2-enyl Methyl Chloroacetate

Li Yongsheng;Li Hong;He Binglin

State Key Laboratory of Functional Polymeric Materials for Adsorption and Separation, Institute of Polymer Chemistry, Nankai University.Tianjin(300071)

Published:2002-08-15

Abstract

Atom transfer radical polymerization (ATRP) of styrene (S) and methyl methacrylate (MMA) initiated by 5-norborn-2-enyl methyl chloroacetate (NMCA) is reported for the first time. The variation of monomer conversion with reaction time and that of molecular weight with monomer conversion were investigated in detail. Experimental results show that the molecular weight distribution (MWD) of the product of ATRP of MMA initiated by NMCA is pretty broad (PDI = 1.80 ～ 2.45) and the deviation of the value of MW detected (GPC) from that of the calculated is pretty large. While ATRP of styrene showing the characteristics of living polymerization, the MWD of the product is narrow (PDI = 1.54), the value of MW detected is in good accordance with that of the calculated, both the variation of monomer conversion with time and MW of the polymer with monomer conversion show a linear relationship. NMR characterization of the synthesized products shows that the double bond in the norbornene rig of the product polymers is not affected by the ATRP conducted.

Key words: FREE REDICAL POLYMERIZATION, STYRENE, METHYLMETHACRYLATE, NMR SPECTROMETRY

CLC Number:

O631.3

Cite this article

Li Yongsheng;Li Hong;He Binglin. Atom Transfer Radical Polymerization of Styrene and Methyl Methacrylate Initiated by 5-Norborn-2-enyl Methyl Chloroacetate[J]. Acta Chimica Sinica, 2002, 60(8): 1485-1489.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Chunhui Yang, Jingchao Chen, Xinhan Li, Li Meng, Kaimin Wang, Weiqing Sun, Baomin Fan. Difluoroallylation of Silanes under Photoirradiation [J]. Acta Chimica Sinica, 2023, 81(1): 1-5.
[2]	Liu Qingqing, Zhang Yihan, Gao Can, Wang Tianyu, Hu Wenping, Dong Huanli. Synthesis and Property Study of Field-effect Emissive Conjugated Polymers Based on Styrene and Benzothiadiazole [J]. Acta Chimica Sinica, 2020, 78(9): 945-953.
[3]	Huang Hao, Lin Huaxin, Wang Min, Liao Jian. Copper-Catalyzed Enantioselective Aminoboration of Styrenes with 1,2-Benzisoxazole as Nitrogen Source [J]. Acta Chimica Sinica, 2020, 78(11): 1229-1234.
[4]	Luo Jianxin, Yan Wenhai, Ma Qing, Zhang Chunyan, Fang Yiquan, Zhang Xucheng, Wang Changchun. Study on High Activity Monodispersed Sulfonated Porous Polystyrene Microspheres for Preparation of Biodiesel [J]. Acta Chimica Sinica, 2019, 77(1): 54-59.
[5]	Liu Qingyun, Zhao Xianghu, Li Jialu, Cao Song. Synthesis of Cyanated Difluorostyrene Derivatives via S_N2' Cyanomethylation of α-(Trifluoromethyl)styrenes with Acetonitrile [J]. Acta Chim. Sinica, 2018, 76(12): 945-950.
[6]	Zhang Yongling, Wang Min, Cao Peng, Liao Jian. Copper-Catalyzed Enantioselective Aminoboration of Styrenes with Chiral Sulfoxide Phosphine Ligand [J]. Acta Chim. Sinica, 2017, 75(8): 794-797.
[7]	Wang Yifan, Fan Yimei, Jian Jun, Pan Yumin, Zhao Liang, Jing Xueping, Zhou Shengjia, Chen Xiaohong, Du Quan, Wang Ling, Wu Xiaoju, Fu Xiangkai. Synthesis of Chiral Salen Mn (III) Complex Immobilized on Phenoxy-modified AlPS-PVPA as Catalysts for Epoxidation of Olefins [J]. Acta Chim. Sinica, 2017, 75(7): 715-722.
[8]	Wu Qiong, Zhao Jiajia, Sun Sibing, Tu Mansu, Shi Feng. Catalytic Asymmetric[4+2] Cycloaddition of o-Hydroxybenzyl Alcohols with o-Hydroxyl Styrenes: Diastereo- and Enantioselective Construction of Chiral Chroman Scaffold [J]. Acta Chim. Sinica, 2016, 74(7): 576-581.
[9]	Hu Xianqiao, He Qiaohong, Bai Zeqing, Su Faming, Chen Hengwu. An Approach for Irreversible Bonding of PDMS-PS Hybrid Microfluidic Chips at Room Temperature [J]. Acta Chimica Sinica, 2013, 71(11): 1535-1539.
[10]	Gao Xia, Fan Jing, Wang Xiaolong, Zhang Yanshu . Synthesis of a Novel 1-Ethyl-3-methylimidazolium Chloride Ionic Liquid Molecularly Imprinted Polymer and Its Properties of Specific Adsorption and Solid Phase Extraction [J]. Acta Chimica Sinica, 2013, 71(10): 1411-1420.
[11]	Yan Lin, Kong Hui, Li Zaijun. Synthesis and Supercapacitor Property of Three-dimensional Graphene/Ni-Al Layered Double Hydroxide Composite [J]. Acta Chimica Sinica, 2013, 71(05): 822-828.
[12]	Ma Yuhong, Zhang Bing, Zhao Changwen, Liu Lianying, Jiang Shan, Liang Shujun, Yang Wantai. A Novel Macroinitiator Based on the Copolymer of α-Methylstyrene Synthesis and Its Application in Preparing Block and Graft Polymers [J]. Acta Chimica Sinica, 2013, 71(02): 151-158.
[13]	Wang Xiaofeng, Yuan Qiaolong. Preparation of Polystyrene Nanospheres in Confined Space [J]. Acta Chimica Sinica, 2012, 70(9): 1047-1054.
[14]	Lü Huichao, Zhang Chengpan, Huang Jin, Zhao Qiaoling, Ma Zhi, Xiao Jichang. Polystyrene-co-poly(2,3,4,5,6-pentafluoro styrene) Copolymers: Synthesis and Fabrication of Their Porous Films [J]. Acta Chimica Sinica, 2012, 70(9): 1125-1130.
[15]	Zhu Haitao, Liu Guosheng. Palladium-Catalyzed Oxidative Aminofluorination of Styrenes [J]. Acta Chimica Sinica, 2012, 70(23): 2404-2407.

梳型接枝共聚物的合成（IV）-氯乙酸降冰片烯甲酯引发苯乙烯、甲基丙烯酸甲酯原子转移自由基聚合的研究

Atom Transfer Radical Polymerization of Styrene and Methyl Methacrylate Initiated by 5-Norborn-2-enyl Methyl Chloroacetate

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments