Synthesis of Naphtho[2,3-a]indolizine-7,12-quinones by the Reaction of Pyridinium N-Ylides with 1,4-Naphthoquinone in the Presence of Tetrakispyridine Cobalt (II) Dichromate

Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (6): 889-892. Previous Articles Next Articles

Original Articles

二铬氢四吡啶合钴（II）存在下吡啶叶立德与1,4－萘醌的反应

王炳祥;何婷;胡宏纹

南京大学化学化工学院

发布日期:2003-06-15

Synthesis of Naphtho[2,3-a]indolizine-7,12-quinones by the Reaction of Pyridinium N-Ylides with 1,4-Naphthoquinone in the Presence of Tetrakispyridine Cobalt (II) Dichromate

Wang Binxiang;He Ting;Hu Hongwen

Department of Chemistry, Nanjing University

Published:2003-06-15

Abstract

A one-pot procedure was developed to prepare the derivatives of naphtho[2,3-a]indolizine-7,12-quinones (6a～6d, 8a～8c, 10a～10c) in moderate yields (31%～82%) by a 1, 3-dipolar cycloaddition reaction of pyridinium N-ylides (4a～4(1), isoquinolinium N-ylides (7a～7c) or quinolinium N-ylides (9a～9c) to 1,4-naphthoquinone, followed by an aromatization, in the presence of tetrakispyridine cobalt( H ) dichromate (TPCD).

Key words: PYRIDINE P, COBALT COMPLEX, NAPHTHOQUINONE, INDOLIZINE P, QUINOLINE P

CLC Number:

O621

Cite this article

Wang Binxiang;He Ting;Hu Hongwen. Synthesis of Naphtho[2,3-a]indolizine-7,12-quinones by the Reaction of Pyridinium N-Ylides with 1,4-Naphthoquinone in the Presence of Tetrakispyridine Cobalt (II) Dichromate[J]. Acta Chimica Sinica, 2003, 61(6): 889-892.

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二铬氢四吡啶合钴（II）存在下吡啶叶立德与1,4－萘醌的反应

Synthesis of Naphtho[2,3-a]indolizine-7,12-quinones by the Reaction of Pyridinium N-Ylides with 1,4-Naphthoquinone in the Presence of Tetrakispyridine Cobalt (II) Dichromate

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