Novel MCM-41 Supported Niobium Acid for the Catalytic Oxidation of Cyclopentene to Glutaraldehyde

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (16): 1467-1471. Previous Articles Next Articles

新型MCM-41固载化铌酸催化氧化环戊烯制备戊二醛

徐建华, 戴维林, 杨新丽, 曹勇, 范康年

复旦大学化学系, 上海市分子催化和功能材料重点实验室, 上海, 200433

投稿日期:2003-12-31 修回日期:2004-04-27 发布日期:2014-02-17
通讯作者: wldai@fudan.edu.cn
作者简介:戴维林:E-mail:wldai@fudan.edu.cn;Tel:021-65643792-6;Fax:021-65641740.
基金资助:
国家重点基础研究发展规划"973"项目(No.2003CB615807)、上海市科委基础研究重点项目(No.02DJ14021)以及上海市教委曙光计划02SG04资助项目.

Novel MCM-41 Supported Niobium Acid for the Catalytic Oxidation of Cyclopentene to Glutaraldehyde

XU Jian-Hua, DAI Wei-Lin, YANG Xin-Li, CAO Yong, FAN Kang-Nian

Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433

Received:2003-12-31 Revised:2004-04-27 Published:2014-02-17

Abstract

Niobium acid has been doped in MCM-41 for the synthesis of novel efficient Nb₂O₅/MCM-41 catalyst by using aqueous Nb-oxalic acid compounds as the precursor.The catalyst has been characterized by means of XRD, BET, N₂-adsorption and desorption methods and shows a satisfying catalytic performance in the selective oxidation of cyclopentene to glutaraldehyde.The conversion reaches 100% and the yield has come up to 50%, suggesting its favorable application potential in industry.

Key words: niobium acid, MCM-41, cyclopentene, glutaraldehyde, selective oxidation, H₂O₂

Cite this article

XU Jian-Hua, DAI Wei-Lin, YANG Xin-Li, CAO Yong, FAN Kang-Nian. Novel MCM-41 Supported Niobium Acid for the Catalytic Oxidation of Cyclopentene to Glutaraldehyde[J]. Acta Chimica Sinica, 2004, 62(16): 1467-1471.

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新型MCM-41固载化铌酸催化氧化环戊烯制备戊二醛

Novel MCM-41 Supported Niobium Acid for the Catalytic Oxidation of Cyclopentene to Glutaraldehyde

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