Raman Study of Transformation Behaviors of Tungsten-containing Peroxo Species Affected by Different Precursors and Solution Acidities

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (18): 1780-1784. Previous Articles Next Articles

溶液pH值及钨前驱体影响含钨过氧物种结构的Raman光谱研究

林海强¹, 李华明², 于贤勇¹, 翟和生¹, 袁友珠¹, 万惠霖¹

1. 厦门大学化学系, 固体表面物理化学国家重点实验室, 厦门, 361005;
2. 海南师范学院化学系, 海口, 571158

投稿日期:2003-11-10 修回日期:2004-05-12 发布日期:2014-02-17
通讯作者: 林海强,E-mail:hqlin@jingxian.xmu.edu.cn E-mail:hqlin@jingxian.xmu.edu.cn
基金资助:
福建省自然科学基金(No.E0110005)资助项目.

Raman Study of Transformation Behaviors of Tungsten-containing Peroxo Species Affected by Different Precursors and Solution Acidities

LIN Hai-Qiang¹, LI Hua-Ming², YU Xian-Yong¹, ZHAI He-Sheng¹, YUAN You-Zhu¹, WAN Hui-Lin¹

1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiaman 361005;
2. Department of Chemistry, Hainan Normal University, Haikou 571158

Received:2003-11-10 Revised:2004-05-12 Published:2014-02-17

Abstract

Tungsten and molybdenum compounds act as efficient catalysts for oxidations of olefins, alcohols or aldehydes by hydrogen peroxide. The nature of the peroxo species formed in solutions with different precursors including Na₂WO₄, (NH₄)₁₀[H₂W₁₂O₄₂] and H₃PW₁₂O₄0 in the presence of excess H₂O₂ has been studied by Raman spectroscopy. Regardless of tungsten-containing precursors, mononuclear species of [WO₂(O₂)₂(H₂O)]^2- is likely principal peroxo species under the conditions with low pH (pH<2.3) and excess H₂O₂, and other dimeric or polymeric species are almost absent. Moreover, novel method for determining H₂O₂ concentrations by Raman spectroscopic analysis was established and applied in kinetics study of H₂O₂ catalytic dismutation to H₂O and O₂.

Key words: hydrogen peroxide, peroxo species, heteropoly acid, Raman spectrum

Cite this article

LIN Hai-Qiang, LI Hua-Ming, YU Xian-Yong, ZHAI He-Sheng, YUAN You-Zhu, WAN Hui-Lin. Raman Study of Transformation Behaviors of Tungsten-containing Peroxo Species Affected by Different Precursors and Solution Acidities[J]. Acta Chimica Sinica, 2004, 62(18): 1780-1784.

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溶液pH值及钨前驱体影响含钨过氧物种结构的Raman光谱研究

Raman Study of Transformation Behaviors of Tungsten-containing Peroxo Species Affected by Different Precursors and Solution Acidities

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