Investigation of Structures of the Self-assembled Pseudorotaxane of Cucurbiturils with Some Alkyldiamines

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (19): 1927-1934. Previous Articles Next Articles

瓜环与长链二胺自组装实体结构考察

徐周庆¹, 姚晓青¹, 薛赛凤¹, 祝黔江¹, 陶朱¹, 张建新², 魏赞斌³, 龙腊生³

1. 贵州大学应用化学研究所, 贵阳, 550025;
2. 中国科学院贵州省天然产物重点实验室, 贵阳, 550002;
3. 厦门大学化学与化工学院, 厦门, 361005

投稿日期:2003-12-12 修回日期:2004-05-26 发布日期:2014-02-17
通讯作者: 薛赛凤,E-mail:gzutao@263.net E-mail:gzutao@263.net
基金资助:
国家自然科学基金(No.200261002)、贵州省重点基金(No.20023004)、贵州省国际合作(No.200211003)资助项目.

Investigation of Structures of the Self-assembled Pseudorotaxane of Cucurbiturils with Some Alkyldiamines

XU Zhou-Qing¹, YAO Xiao-Qing¹, XUE Sai-Feng¹, ZHU Qian-Jiang¹, TAO Zhu¹, ZHANG Jian-Xin², WEI Zhan-Bin³, LONG La-Sheng³

1. Institute of Applied Chemistry, Guizhou University, Guiyang 550025;
2. Key Laboratory of Chemistry for Natural Products of Guizhou Province, Guiyang 550002;
3. Department of Chemistry, Xiamen University, Xiamen 361005

Received:2003-12-12 Revised:2004-05-26 Published:2014-02-17

Abstract

The structures of self-assembled pseudorotaxane of cucurbit[n]urils(n=6～8) with some alkyldiamines have been investigated by ¹H NMR technique and single crystal X-ray diffraction method. The results reveal that the interaction between cucurbit[6]uril or cucurbit[7]uril and 1,7-diaminoheptane or 1,8-diaminooctane is stronger than that between cucurbit[8]uril and 1,7-diaminoheptane or 1,8-diaminooctane, and the pseudorotaxanes of cucurbit[n]urils with the alkyldiamines were observed. Particularly, in the pseudorotaxane of cucurbit[6]uril with 1,8-diaminooctane, the amino groups of 1,8-diaminooctane are left outside the ports of cucurbit[6]uril.

Key words: cucurbit[n]uril, alkyldiamine, NMR technique, single crystal X-ray diffraction, pseudorotaxane

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XU Zhou-Qing, YAO Xiao-Qing, XUE Sai-Feng, ZHU Qian-Jiang, TAO Zhu, ZHANG Jian-Xin, WEI Zhan-Bin, LONG La-Sheng. Investigation of Structures of the Self-assembled Pseudorotaxane of Cucurbiturils with Some Alkyldiamines[J]. Acta Chimica Sinica, 2004, 62(19): 1927-1934.

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瓜环与长链二胺自组装实体结构考察

Investigation of Structures of the Self-assembled Pseudorotaxane of Cucurbiturils with Some Alkyldiamines

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