Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (20): 1906-1912. Previous Articles     Next Articles

Original Articles

UV辐照接枝制备酚酞基聚芳醚酮纳滤膜——链转移剂的作用

邱长泉,平郑骅*,张力恒   

  1. (复旦大学高分子科学系 教育部聚合物分子工程重点实验室 上海 200433)
  • 投稿日期:2004-12-30 修回日期:2005-06-20 发布日期:2010-12-10
  • 通讯作者: 平郑骅

Preparation of PEK-C Nanofiltration Membrane by UV Irradiation Graft-Polymerization and Influence of Transfer Agent

QIU Chang-Quan, PING Zheng-Hua*, ZHANG Li-Heng   

  1. (Key Laboratory of Molecular Engineering of Polymers, Ministry of Education, Department of Macromolecular Science,
    Fudan University, Shanghai 200433)
  • Received:2004-12-30 Revised:2005-06-20 Published:2010-12-10
  • Contact: PING Zheng-Hua

Hydrophilic nanofiltration membranes with good retention to bivalent salts were prepared by graft polymerization of acrylic acid (AA) onto surface of cardo polyetherketone (PEK-C) ultrafiltration membranes. The influence of isopropanol (i-PrOH) as transfer agent on the graft polymerization and the performance of nanofiltration membranes were studied. The results of FTIR-ATR, contact angle, SEM and AFM showed that the presence of i-PrOH did not disturb the graft polymerization of AA. It was in favor of membrane permeation increase. Although the retention to salts was a little decreased, it could be improved by increasing the irradiation time or irradiation intensity. It was found that when the weight ratio of i-PrOH over AA was higher than 0.75, the flux of modified membrane was linearly increased with i-PrOH concentration while the retention to salt was kept unchanged. It was suggested that the transfer reaction of i-PrOH should increase grafting density and surface charge, which would be in favor of salt retention.

Key words: photo-induced polymerization, ultrafiltration membrane, nanofiltration membrane, cardo polyetherketone, acrylic acid, isopropanol