share
Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (20): 1906-1912. Previous Articles Next Articles
Original Articles
邱长泉,平郑骅*,张力恒
投稿日期:
修回日期:
发布日期:
通讯作者:
QIU Chang-Quan, PING Zheng-Hua*, ZHANG Li-Heng
Received:
Revised:
Published:
Contact:
Share
Hydrophilic nanofiltration membranes with good retention to bivalent salts were prepared by graft polymerization of acrylic acid (AA) onto surface of cardo polyetherketone (PEK-C) ultrafiltration membranes. The influence of isopropanol (i-PrOH) as transfer agent on the graft polymerization and the performance of nanofiltration membranes were studied. The results of FTIR-ATR, contact angle, SEM and AFM showed that the presence of i-PrOH did not disturb the graft polymerization of AA. It was in favor of membrane permeation increase. Although the retention to salts was a little decreased, it could be improved by increasing the irradiation time or irradiation intensity. It was found that when the weight ratio of i-PrOH over AA was higher than 0.75, the flux of modified membrane was linearly increased with i-PrOH concentration while the retention to salt was kept unchanged. It was suggested that the transfer reaction of i-PrOH should increase grafting density and surface charge, which would be in favor of salt retention.
Key words: photo-induced polymerization, ultrafiltration membrane, nanofiltration membrane, cardo polyetherketone, acrylic acid, isopropanol
QIU Chang-Quan, PING Zheng-Hua*, ZHANG Li-Heng. Preparation of PEK-C Nanofiltration Membrane by UV Irradiation Graft-Polymerization and Influence of Transfer Agent[J]. Acta Chimica Sinica, 2005, 63(20): 1906-1912.
Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks