Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (11): 1322-1326. Previous Articles     Next Articles

镝掺杂铁氧体纳米晶的制备、表征和磁性

蒋荣立*,陈文龙,张宗祥,孙强,尹文萱   

  1. (中国矿业大学化工学院 徐州 221116)
  • 投稿日期:2007-10-21 修回日期:2007-12-04 发布日期:2008-06-14
  • 通讯作者: 蒋荣立

Preparation, Characterization and Magnetic Properties of Ferrite Nanocrystals Doped with Dysprosium

JIANG, Rong-Li*; CHEN, Wen-Long; ZHANG, Zong-Xiang; SUN, Qiang; YIN, Wen-Xuan   

  1. (School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116)
  • Received:2007-10-21 Revised:2007-12-04 Published:2008-06-14
  • Contact: JIANG, Rong-Li

Dy3+-doped ferrite nanocrystals were prepared by a chemical co-precipitation method and characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Gouy magnetic balance, vibrating sample magnetometer (VSM), and X-ray energy spectrum (EDX), respectively. The effects of dysprosium contents on structure, magnetic properties and size of the ferrite were investigated. The results show that Dy3+can enhance the magnetic properties which are strongest while n(Fe3+)∶n(Dy3+) is 14∶1 among the samples prepared, and weaken the coercive force of the spinel ferrite. Dy3+ fills in the spinel ferrite lattice and mostly enters B site. The size of the Dy-doped ferrite nanoparticles becomes smaller and their distribution is more concentrated and uniform. The average diameter of the ferrite nanoparticles is 14 nm before doping and reduces to 8 nm after doping when n(Fe3+)∶n(Dy3+) is 14∶1. The results support the concept that the soft magnetic ferrite nanocrystals with superparamagnetism can be applied to nanometer magnetic fluid field.

Key words: spinel, ferrite, dysprosium, doping, magnetic property