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Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (14): 1431-1436. Previous Articles Next Articles
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陈沛然*,张怡,周辉,徐青
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中央高校基本科研业务费专项资金
CHEN Pei-Ran, ZHANG Yi, ZHOU Hui, XU Qing
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Kinetic resolution of a series of benzyl alcohols bearing functional group on α-position catalyzed by (R)-benzotetramisole catalyst has been investigated. The competition between the cation-π interaction of the aryl ring of the substrates with the catalyst and the cation-π interaction of the functional group s π-system with the catalyst led to the decrease of the stereo-selectivity of the reaction and the configuration change of the products.
Key words: kinetic resolution, benzyl alcohols, (R)-benzotetramisole catalyst
CHEN Pei-Ran, ZHANG Yi, ZHOU Hui, XU Qing. A Study on the Kinetic Resolution of Benzyl Alcohols Bearing Functional Group on α-Position Catalyzed by (R)-Benzotetramisole Catalyst[J]. Acta Chimica Sinica, 2010, 68(14): 1431-1436.
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