Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (22): 2356-2362. Previous Articles     Next Articles

Full Papers

界面作用对PMMA/MCM-41/OMMT复合材料性能的影响

王娜1,2*,苗頔1,李洪伟1,方庆红1,2,陈尔凡1,2   

  1. (1沈阳化工大学材料科学与工程学院 沈阳 110142 )
    (2辽宁省高校高分子材料应用技术重点实验室 沈阳化工大学 沈阳 110142)
  • 投稿日期:2010-04-19 修回日期:2010-06-20 发布日期:2010-07-25
  • 通讯作者: 王娜 E-mail:iamwangna@sina.com

Effect of Interfacial Interaction on the Properties of PMMA/MCM-41/OMMT

Wang Na*,1,2 Miao Di1 Li Hongwei1 Fang Qinghong1,2 Chen Erfan1,2   

  1. (1School of Material Science/Engineering, Shenyang University of Chemical Technology, Shenyang 110142)
    (2 Education Department of LiaoNing Province, Key Laboratory of Applied Technology of Polymer Materials, Shenyang University of Chemical Technology, Shenyang 110142)
  • Received:2010-04-19 Revised:2010-06-20 Published:2010-07-25

Polymethylmethacrylate (PMMA)/organic montmorillonite (OMMT), PMMA/MCM-41 (without template), PMMA/OMMT/MCM-41 (without template) composites were prepared by in situ polymerization. The interfacial interaction between fillers and PMMA matrix and the effect of mechanical properties and thermal stability of PMMA composite were investigated. It was demonstrated that when OMMT/MCM-41 mixture was used as filler, novel nano-network structure was formed between the matrix and the filler. Synergistic reinforcing effect was obtained due to the strong interfacial interaction between the matrix and the filler. When the amount of OMMT/MCM-41 mixture [w(OMMT)∶w(MCM-41)=1∶1] was 0.5%, tensile strength of the nano-composite approached maximum values of 49.0 MPa, increased by 15%. Effect of adding different kinds of fillers on thermal properties of the nano-composites were also studied. Thermal stability of the nano-composite was higher by adding OMMT/MCM-41 mixture than that of composite by only adding either OMMT or MCM-41.

Key words: PMMA, OMMT, MCM-41, interfacial interaction, nano-composite