Synthesis of Novel Photochromic Spiropyran Compounds and Their Application Study

doi:10.6023/A1110111

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (9): 1095-1103.DOI: 10.6023/A1110111 Previous Articles Next Articles

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新型螺吡喃化合物的合成及应用研究

谭春斌^a, 赵泽琳^a, 高峻^a, 雷景新^b

a. 四川大学化学工程学院成都 610065;
b. 四川大学高分子材料工程国家重点实验室成都 610065

投稿日期:2011-10-11 修回日期:2012-01-12 发布日期:2012-01-31
通讯作者: 高峻

Synthesis of Novel Photochromic Spiropyran Compounds and Their Application Study

Tan Chunbin^a, Zhao Zelin^a, Gao Jun^a, Lei Jingxin^b

a. Chemical Engineering Institute of Sichuan University, Chengdu 610065;
b. The State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065

Received:2011-10-11 Revised:2012-01-12 Published:2012-01-31

The several kinds of new novel spiropyran (SP) compounds were first designed and synthesized. The structures of these target compounds were characterized by ¹H NMR, IR and MS tests. The photochromic properties of target compounds and their influencing factors were studied, and the applications of SP1 on the polymer materials field were initially investigated. The results show that λ_max in UV-vis absorption spectra will shift to longer wavelengths as the result of benzopyran ring linked with strong electrowithdrawing groups; the thermal fade rate is slower with N atom linked with flexible long group; SP1 has good fatigue resistance compared with the other kinds of the target compounds. The fading rate of both SP-g-hPMMA and SP-m-PMMA are obviously slower than that of SP1. The tensile strength and elongation at break of SP-g-hPMMA and SP-m-PMMA were almost unchanged compared with that of PMMA. It is expected that SP-g-hPMMA and SP-m-PMMA will be applied in the field of polymer photochromic materials.

Key words: spiropyran, photochromism compound, synthesis, PMMA

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Tan Chunbin, Zhao Zelin, Gao Jun, Lei Jingxin. Synthesis of Novel Photochromic Spiropyran Compounds and Their Application Study[J]. Acta Chimica Sinica, 2012, 70(9): 1095-1103.

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新型螺吡喃化合物的合成及应用研究

Synthesis of Novel Photochromic Spiropyran Compounds and Their Application Study

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