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Acta Chimica Sinica ›› 1997, Vol. 55 ›› Issue (6): 611-616. Previous Articles Next Articles
Original Articles
刘志煜;李恒光;陈淑华
发布日期:
Liu Zhiyu;Li Hengguang;Chen Shuhua
Published:
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p-Benzoquinone reacted with cyclopentadiene to mask its double bond. After introduction of the necessary functional groups and substituent, retro Diels-Alder reaction gave (± )-epiepoformin, which was converted into (±)-epoformin by inversion of its hydroxy configuration in 70% and 65% overall yields, respectively.
Key words: NATURAL PRODUCTS, DIELS-ALDER REACTION, CYCLOPENTADIENE, BENZOQUINONE
CLC Number:
O629
Liu Zhiyu;Li Hengguang;Chen Shuhua. Natural products synthesis by retro Diels-Alder reaction XIV. Stereospecific synthesis of (±)-epoformin and (± )-epiepoformin[J]. Acta Chimica Sinica, 1997, 55(6): 611-616.
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