Investigation of the Electrocatalytic Behavior of Halogenated Acids at a (C_(70))_2-p-tert-calix[8]arene Chemically Modified Electrode

Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (3): 389-392. Previous Articles Next Articles

Original Articles

(C_(70))_2-对叔丁基杯[8]芳烃化学修饰电极对卤代酸的电催化行为

罗红霞;李南强;施祖进;顾镇南;周锡煌

北京大学化学系.北京(100871)

发布日期:2002-03-15

Investigation of the Electrocatalytic Behavior of Halogenated Acids at a (C_(70))_2-p-tert-calix[8]arene Chemically Modified Electrode

Luo Hongxia;Li Nanqiang;Shi Zujin;Gu Zhennan;Zhou Xihuang

Department of Chemistry, Peking University.Beijing(100871)

Published:2002-03-15

Abstract

The (C_(70))_2-p-tert-butylcalix [8] arene chemically modified electrode had two couples of redox reactions in mixed solvents of MeCN and water (2:3, volume fraction), corresponded to two-and four- electron transfer, respectively. The modified electrode was characterized by the scanning electron microscope and X-ray photoelectron spectroscopy. Both the reduction steps of (C_(70))_2-p- tert-butylcalix [8] arene exhibited catalytic activity towards the reduction of halogenated acid.

Key words: calixarene, CHEMICAL MODIFIED ELECTRODE, ELECTRO-CATALYSIS, CYCLOVOLTAMGRAPH, CHARGE TRANSFER REACTION, SEM

CLC Number:

O646

Cite this article

Luo Hongxia;Li Nanqiang;Shi Zujin;Gu Zhennan;Zhou Xihuang. Investigation of the Electrocatalytic Behavior of Halogenated Acids at a (C_(70))_2-p-tert-calix[8]arene Chemically Modified Electrode[J]. Acta Chimica Sinica, 2002, 60(3): 389-392.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Yongxue Li, Yu Liu. Supramolecular Secondary Assembly Based on Amphiphilic Calix[4]arenes and Its Biological Applications^★ [J]. Acta Chimica Sinica, 2023, 81(8): 928-936.
[2]	Liwei Hu, Xianhu Liu, Chuntai Liu, Yanlin Song, Mingzhu Li. Self-assembly Fabrication and Applications of Photonic Crystal Structure Color Materials^★ [J]. Acta Chimica Sinica, 2023, 81(7): 809-819.
[3]	Lanying Li, Qing Tao, Yanli Wen, Lele Wang, Ruiyan Guo, Gang Liu, Xiaolei Zuo. Poly-adenine-based DNA Probes and Their Applications in Biosensors^★ [J]. Acta Chimica Sinica, 2023, 81(6): 681-690.
[4]	Dongrui Su, Xiaokang Ren, Yunhao Yu, Luyang Zhao, Tianyu Wang, Xuehai Yan. Tyrosine Derivative Regulated Enzyme Catalytic Pathway for Controllable Synthesis of Functional Melanin^★ [J]. Acta Chimica Sinica, 2023, 81(11): 1486-1492.
[5]	Xu Pu, Zejuan Li, Junqiu Shi, Yunqing Zhu, Jianzhong Du. Recent Advances in Organ-Targeting Polymeric Delivery Vectors for Nucleic Acids^★ [J]. Acta Chimica Sinica, 2023, 81(10): 1438-1446.
[6]	Lixuan Liu, Yang Yang, Zhixiang Wei. Chiral Organic Optoelectronic Materials and Circularly Polarized Light Luminescence and Detection [J]. Acta Chimica Sinica, 2022, 80(7): 970-992.
[7]	Jiaxian Sun, Yuting Liu, Zhigang Yin, Qingdong Zheng. High-Performance Flexible Photonic Synapse Transistors Based on a Bulk Composite Film of Organic Semiconductors with Complementary Absorption [J]. Acta Chimica Sinica, 2022, 80(7): 936-945.
[8]	Jamshid Kadirkhanov, Feng Zhong, Wenjian Zhang, Chunyan Hong. Preparation of Multi-chambered Vesicles by Polymerization-induced Self-assembly and the Influence of Solvophilic Fragments in the Core-forming Blocks [J]. Acta Chimica Sinica, 2022, 80(7): 913-920.
[9]	Yuze Liu, Kunhua Li, Jiaxing Huang, Xi Yu, Wenping Hu. Accurate Prediction of the Boiling Point of Organic Molecules by Multi-Component Heterogeneous Learning Model [J]. Acta Chimica Sinica, 2022, 80(6): 714-723.
[10]	Yu Qi, Fuxiang Zhang. Photocatalytic Water Splitting for Hydrogen Production^※ [J]. Acta Chimica Sinica, 2022, 80(6): 827-838.
[11]	Xicheng Feng, Liangliang Zhu, Bingbing Yue. Circularly Polarized Luminescence and Dynamic Regulation Based on the co-Assembly of L/D-Lysine Hydrochloride and Photoactivated AIE Molecules [J]. Acta Chimica Sinica, 2022, 80(5): 647-651.
[12]	Zhiqin Wang, Bo Xiang, Xiaoyu Huang, Guolin Lu. Effect of Phosphotungstic Acid on Self-seeding of Oligo(p-phenylenevinylene)-b-poly(2-vinylpyridine)^※ [J]. Acta Chimica Sinica, 2022, 80(3): 297-302.
[13]	Shanwu Li, Chenyujie Zhu, Yinhao Luo, Yaru Zhang, Hanming Teng, Zongrui Wang, Yonggang Zhen. Research Progress in n-type Organic Semiconducting Materials Based on Amides or Imides [J]. Acta Chimica Sinica, 2022, 80(12): 1600-1617.
[14]	Fengqiao Zhu, Wengui Wang, Xudong Qu, Shoufeng Wang. Research Progress in Chemical Semi-synthetic Modification of Thiopeptide Antibiotics [J]. Acta Chimica Sinica, 2022, 80(10): 1448-1462.
[15]	Dong Yin, Hongyi Shang, Wenhao Yu, Shikai Xiang, Ping Hu, Keqing Zhao, Chun Feng, Biqin Wang. Synthesis, Mesomorphism and Gelation Properties of Triazole-Modified Triphenylene 2,3-Dicarboxylic Esters and 2,3-Dicarboxyimides [J]. Acta Chimica Sinica, 2022, 80(10): 1376-1384.

(C_(70))_2-对叔丁基杯[8]芳烃化学修饰电极对卤代酸的电催化行为

Investigation of the Electrocatalytic Behavior of Halogenated Acids at a (C_(70))_2-p-tert-calix[8]arene Chemically Modified Electrode

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments