Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (5): 939-946. Previous Articles     Next Articles

Original Articles

Schiff碱N-氧化吡啶-2-甲醛缩氨基脲及其铜配合物的合成、晶体结构及谱学性质的研究

梁宏;陈雄斌;胡瑞祥;陈振锋;郁开北   

  1. 广西师范大学化学系,桂林(541004);中国科学院成都分析测试中心,成都 (610041)
  • 发布日期:2002-05-15

Synthesis, Crystal Structure and Spectroscopic properties of a Copper(II) Complex of the Schiff base Derived from Picolinaldehyde N- oxide and Semicarbazone

Liang Hong;Chen Xiongbin;Hu Ruixiang;Chen Zhenfeng;Yu Kaibei   

  1. Department of chemistry, Guangxi Normal University,Guilin(541004)
  • Published:2002-05-15

The titled Schiff base derived from picolinaldehyde N-oxide with semicarbazone (PNOS) and it's copper(II) complex [Cu(PNOS)(NO_3)_2] have been synthesized. X-ray diffraction study shows that PNOS molecules form a bilayer 2D network via classical H-bonds, and further assemble to give a 3D infinite network through unclassical H-bonds. In the complex, PNOS is coordinated to copper(II) via the N-O oxygen, the C=N nitrogen and the C=O oxygen atoms, with one nitrate group serving as monodentate ligand, and the other as a bidentate ligand. The coordination geometry is a distorted octahedron. In the crystal, the complex molecules assemble to form a monolayer net via classical H- bonds and the monolayer net further forms a bilayer network through unclassical H-bonds.

Key words: COPPER COMPLEX, PYRIDINE P, FORMALDEHYDE P, SEMICARBAZIDE P, SCHIFF BASE, RETICULAR FORMATION, XRD

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