Syntheses and Characterization of Two Palladium Complexes of Isonitrosoacetylacetoneimine

Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (5): 947-949. Previous Articles Next Articles

Original Articles

两个Pd(II)的异亚硝基乙酰丙酮亚胺配合物的合成和表征

冯云龙;刘世雄

福州大学中心实验室,福州(350002)

发布日期:2002-05-15

Syntheses and Characterization of Two Palladium Complexes of Isonitrosoacetylacetoneimine

Feng Yunlong;Liu Shixiong

Central laboratory, Fuzhou University,Fuzhou(350002)

Published:2002-05-15

Abstract

Two palladium complexes of isonitrosoacetylacetoneimine, Pd(o- BrC_6H_4-IAI)_2 (1) and Pd(C_6H_5CH_2-IAI)_2 (2), were synthesized and characterized by IR and Raman spectra. Complex 1 crystallizes in monoclinic system, space group P2_1/c, with parameters: a = 0.8013(2) nm, b = 1.8775(4) nm, c = 0.7905(2) nm, β = 98.22(3)°, V = 1.1770(5) nm~3, Z = 2, D_c = 1.892 g·cm~(-3)and F(000) = 656. The final R value is 0.0663 for 1742 observed reflections with I ≥ 2σ(I). The Pd (II) atoms have trans distorted square-planar PdN_4 coordination composed of imino-nitrogen atoms and oximo-nitrogen atoms from the two Schiff base ligands.

Key words: CRYSTAL STRUCTURE, PALLADIUM COMPLEX, IMINE, ACETOPREPANONE

CLC Number:

O611.662

Cite this article

Feng Yunlong;Liu Shixiong. Syntheses and Characterization of Two Palladium Complexes of Isonitrosoacetylacetoneimine[J]. Acta Chimica Sinica, 2002, 60(5): 947-949.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Yang Liu, Fengqin Gao, Zhanying Ma, Yinli Zhang, Wuwu Li, Lei Hou, Xiaojuan Zhang, Yaoyu Wang. Co-based Metal-organic Framework for High-efficiency Degradation of Methylene Blue in Water by Peroxymonosulfate Activation [J]. Acta Chimica Sinica, 2024, 82(2): 152-159.
[2]	Zihao Wang, Min Chen, Changle Chen. Catalytic Synthesis of Polyolefin Elastomer Using Unsymmetrical α-Diimine Nickel Catalyst^★ [J]. Acta Chimica Sinica, 2023, 81(6): 559-564.
[3]	Yuyin Wang, Xiaoqiang Hu, Hongliang Mu, Yan Xia, Yue Chi, Zhongbao Jian. Enhancement on Nickel-Mediated Ethylene Polymerization by Concerted Steric Hindrance and Fluorine Effect [J]. Acta Chimica Sinica, 2022, 80(6): 741-747.
[4]	Tiantian Lü, Wen Ma, Dongsun Zhan, Yanmin Zou, Jilong Li, Meiling Feng, Xiaoying Huang. Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs⁺ Ions^※ [J]. Acta Chimica Sinica, 2022, 80(5): 640-646.
[5]	Jinxu Zhao, Mingshu Zhang, Wenfa Chen, Xiaoming Jiang, Binwen Liu, Guocong Guo. KAg₃Ga₈S₁₄: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold^※ [J]. Acta Chimica Sinica, 2022, 80(3): 259-264.
[6]	Rong Zhang, Jiangping Liu, Ziyi Zhu, Shumei Chen, Fei Wang, Jian Zhang. Synthesis, Structure and Characterization of Two Ferrocene Functionalized Cadmium Metal Organic Frameworks^※ [J]. Acta Chimica Sinica, 2022, 80(3): 249-254.
[7]	Junyao Xie, Xiaoming Zeng, Meiming Luo. Ni-Catalysed Regioselective α,β-Diarylation of α,β-Unsaturated Aldehydes [J]. Acta Chimica Sinica, 2021, 79(9): 1118-1122.
[8]	Jing Fang, Wenjuan Zhao, Minghao Zhang, Qianrong Fang. A Novel Amide-functionalized Covalent Organic Framework for Selective Dye Adsorption [J]. Acta Chimica Sinica, 2021, 79(2): 186-191.
[9]	Fu Jingru, Ben Teng. Fabrication of a Novel Covalent Organic Framework Membrane and Its Gas Separation Performance [J]. Acta Chimica Sinica, 2020, 78(8): 805-814.
[10]	Li Zhewei, Wang Qianyue, Pu Min, Yang Zuoyin, Lei Ming. Theoretical Study on Nitrogenous Heterocyclic Assisted Aldimine Condensation [J]. Acta Chimica Sinica, 2020, 78(5): 437-443.
[11]	Chen Guanghui, He Yanping, Zhang Lei, Zhang Jian. Syntheses and Structural Studies of a Series of Ti₄(embonate)₆-based Complexes [J]. Acta Chimica Sinica, 2020, 78(12): 1411-1417.
[12]	Wang Zhitao, Li Hui, Yan Shichen, Fang Qianrong. Synthesis of a Two-dimensional Covalent Organic Framework with the Ability of Conducting Proton along Skeleton [J]. Acta Chimica Sinica, 2020, 78(1): 63-68.
[13]	Hu Shu-Boa, Chen Mu-Wang, Zhai Xiao-Yong, Zhou Yong-Gui. Synthesis of Tetrahydropyrrolo/indolo[1,2-a]pyrazines by Enantioselective Hydrogenation of Heterocyclic Imines [J]. Acta Chim. Sinica, 2018, 76(2): 103-106.
[14]	Yu Sifan, Fu Xiang, Liu Gengxin, Qiu Huang, Hu Wenhao. Efficient and Facile Synthesis of Chiral Sulfonamides via Asymmetric Multicomponent Reactions [J]. Acta Chim. Sinica, 2018, 76(11): 895-900.
[15]	Shi Minglin, Zhan Gu, Du Wei, Chen Yingchun. Direct Asymmetric Aza-Vinylogous Mannich Reaction of Nitrones from Isatins and Ketimines [J]. Acta Chim. Sinica, 2017, 75(10): 998-1002.

两个Pd(II)的异亚硝基乙酰丙酮亚胺配合物的合成和表征

Syntheses and Characterization of Two Palladium Complexes of Isonitrosoacetylacetoneimine

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments