Studies on ring-bridged bis(cyclopentadienyl) metal (IVB) and iron derivatives

Abstract

Ring-oxadiethylene bridged bis(cyclopentadienyl) chlorides of titanium and zirconium I (M = Ti, Zr) were synthesized from the reaction of the disodium salt O(CH2CH2C5H4Na)2 with TiCl4 and ZrCl4, in THF. A similar reaction of the sulfur analog gave only the product of tetramethylene bridged bis(cyclopentadienyl)dititanium halides. Ring-phenylenedimethylene bridged ferrocene was synthesized from the disodium salt p-, m-C6H4(CH2C5H4Na)2 with FeCl2. The XPS and Moessbauer spectra of some compounds were discussed.

Key words: CYCLOPENTADIENE P, TETRAHYDROFURAN, X-RAY PHOTOELECTRON SPECTROMETRY, METALLOCENES, TITANIUM COMPLEX, ZIRCONIUM COMPLEX, BRIDGE COMPOUNDS, FERROCENE, MOSSBAUER SPECTROMETRY

CLC Number:

O627

Cite this article

CHEN SHOUSHAN;CHEN YOUXIAN;WANG JITAO. Studies on ring-bridged bis(cyclopentadienyl) metal (IVB) and iron derivatives[J]. Acta Chimica Sinica, 1990, 48(6): 582-586.

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