Acta Chimica Sinica ›› 1995, Vol. 53 ›› Issue (11): 1076-1081. Previous Articles     Next Articles

Original Articles

电沉积CuInSe2上H2O2阴极还原时的电化学振荡行为

徐群杰;邓薰南   

  1. 上海电力学院电化学研究室;上海大学电化学研究室
  • 发布日期:1995-11-15

Oscillating behaviour on electrodeposited CuInSe2 thin films during H2O2 cathodic reduction

XU QUNJIE;DENG XUNNAN   

  • Published:1995-11-15

CuInSe2 thin films prepared by electrodeposition method can produce periodically electrochemistry oscillation phenomenna during H2O2 cathodic reduction. The dynamic current-voltage curve from-1.80V to 0.00V(vs.SCE) appears a pronounced current wave. When the potential is set in the oscillating potential region, the cell response may be accounted for, in the equivalent circuit representation, by the presence of negative resistances and inductances with A.C. methods. The negative resistances and inductances may indicate an autocatalytio reaction with an adsorbed intermediate.

Key words: HYDROGEN PEROXIDE, ELECTRO-DEPOSITION, CYCLOVOLTAMGRAPH, ELECTRODE REACTION

CLC Number: