Studies on organosilicon reactive intermediatesⅦ: The stereochemistry of di(α-furyl) silylene added to olefins

Acta Chimica Sinica ›› 1996, Vol. 54 ›› Issue (2): 206-208. Previous Articles

Original Articles

有机硅反应活性中间体的研究Ⅶ: 二(α-呋喃基)硅烯与烯烃加成反应的立体化学

吴世晖;骆玉美;刘菲

复旦大学化学系

发布日期:1996-02-15

Studies on organosilicon reactive intermediatesⅦ: The stereochemistry of di(α-furyl) silylene added to olefins

WU SHIHUI;LUO YUMEI;LIU FEI

Published:1996-02-15

Abstract

Di (α-furyl) silylene was generated by the photolysis of 2,2-di (α-furyl) hexamethyltrisilane. Di (α-furyl) silylene added stereospecifically to cis- and trans-2-butene gives the cor-responding siliranes. Opening of the siliranes by methanol also occurred in stereospecifically cis-fashion.

Key words: ALKENE, FURAN P, STEREOCHEMISTRY, ADDITION REACTION, SILICONE, REACTIVE INTERMEDIATE

CLC Number:

O627

Cite this article

WU SHIHUI;LUO YUMEI;LIU FEI. Studies on organosilicon reactive intermediatesⅦ: The stereochemistry of di(α-furyl) silylene added to olefins[J]. Acta Chimica Sinica, 1996, 54(2): 206-208.

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有机硅反应活性中间体的研究Ⅶ: 二(α-呋喃基)硅烯与烯烃加成反应的立体化学

Studies on organosilicon reactive intermediatesⅦ: The stereochemistry of di(α-furyl) silylene added to olefins

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