A Comparative Study on Electrochemiluminescent Properties of a Series of Ruthenium(II) Complexes

Acta Chimica Sinica ›› 2007, Vol. 65 ›› Issue (12): 1181-1184. Previous Articles Next Articles

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一系列Ru(II)配合物电致化学发光性质的比较研究

陈晓彤, 董彬, 崔孟超, 王科志*, 金林培

(北京师范大学化学学院北京 100875)

投稿日期:2006-06-06 修回日期:2007-01-22 发布日期:2007-06-28
通讯作者: 王科志

A Comparative Study on Electrochemiluminescent Properties of a Series of Ruthenium(II) Complexes

CHEN Xiao-Tong; DONG Bin; CUI Meng-Chao; WANG Ke-Zhi*; JIN Lin-Pei

(College of Chemistry, Beijing Normal University, Beijing 100875)

Received:2006-06-06 Revised:2007-01-22 Published:2007-06-28
Contact: WANG Ke-Zhi

Abstract

Electrochemiluminescent (ECL) properties of 5 structurally related Ru(II) complexes of [Ru(bpy)₂L¹]^2＋, [Ru(bpy)₂L²]^2＋, [Ru(bpy)₂L³]^2＋, [Ru(phen)₂L¹]^2＋and [Ru(phen)₂L²]^2＋(where bpy＝2,2′-bipyridine, phen＝1,10-phenanthroline, L¹＝4-carboxylphenylimidado[4,5-f][1,10]phenanthroline, L²＝3-carboxyl-4-hydroxylphenylimidado[4,5-f][1,10]phenanthroline, and L³＝3,4-dihydroxyphenylimidado- [4,5-f][1,10]phenanthroline) have been studied in CH₃CN/H₂O (V/V, 1∶1) by using oxalate as coreactant. The results indicate that the presence of hydroxyl in [Ru(bpy)₂L²]^2＋, [Ru(bpy)₂L³]^2＋and [Ru(phen)₂L²]^2＋effectively quenches ECL, and the other complexes exhibit comparable ECL efficiencies to [Ru(bpy)₃]^2＋.

Key words: Ru(II) complex, electrochemiluminescence, bipyridine, phenanthroline

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CHEN Xiao-Tong; DONG Bin; CUI Meng-Chao; WANG Ke-Zhi*; JIN Lin-Pei. A Comparative Study on Electrochemiluminescent Properties of a Series of Ruthenium(II) Complexes[J]. Acta Chimica Sinica, 2007, 65(12): 1181-1184.

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一系列Ru(II)配合物电致化学发光性质的比较研究

A Comparative Study on Electrochemiluminescent Properties of a Series of Ruthenium(II) Complexes

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