Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (12): 1163-1168. Previous Articles     Next Articles

Original Articles

化学动力学中隧道效应的研究 Ⅰ.甲醛单分子热反应中隧道效应的研究

陈玉;赵成大   

  1. 东北师范大学化学系
  • 发布日期:1992-12-15

Study on tunneling effect in the chemical kinetics.Ⅰ.study on tunneling in thermal unimolecular reaction of formaldehyde

CHEN YU;ZHAO CHENGDA   

  • Published:1992-12-15

Using one-dimensional unsym. Eckart potential energy barrier, thermal reaction system of formaldehyde was studied. In addition, a series of rate constants and activation energies have been calculated at different thermal effects and the effect of unsymmetry of potential barrier on the results of calcns. has been discussed in detail. The results of calcns. are in agreement with experimental results.

Key words: REACTION KINETICS, FORMALDEHYDE, REACTION RATE CONSTANT, POTENTIAL BARRIER, TUNNELING EFFECT, HOT REACTION

CLC Number: