The electron energy levels of d^3 configurations in C2v symmetry field and analysis of electronic spectra of CoCl4^2 ion

Acta Chimica Sinica ›› 1991, Vol. 49 ›› Issue (7): 665-670. Previous Articles Next Articles

Original Articles

d^3的C2v电子能级和CoCl4^2电子光谱解析

豆育升;文振翼;张棣

西北大学化学系;西北大学现代物理研究所

发布日期:1991-07-15

The electron energy levels of d^3 configurations in C2v symmetry field and analysis of electronic spectra of CoCl4^2 ion

DOU YUSHENG;WEN ZHENYI;ZHANG DI

Published:1991-07-15

Abstract

The energy matrixes were calculated for the d3 configurations in C2v symmetry field by use of the unitary group approach. The perturbation Hamiltonian consists of Coulomb, crystal and spin-orbit coupling operators. On basis of these energy matrixes, electronic spectra of CoCl42- ion were assigned.

Key words: CARBON ATOM, ELECTRON CONFIGURATION, PERTURBATION THEORY, ELECTRON SPECTROSCOPY, LIGAND FIELD THEORY, COBALT CHLORIDE, ENERGY MATRIX, CESIUM COMPLEX

CLC Number:

O641

Cite this article

DOU YUSHENG;WEN ZHENYI;ZHANG DI. The electron energy levels of d^3 configurations in C2v symmetry field and analysis of electronic spectra of CoCl4^2 ion[J]. Acta Chimica Sinica, 1991, 49(7): 665-670.

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d^3的C2v电子能级和CoCl4^2电子光谱解析

The electron energy levels of d^3 configurations in C2v symmetry field and analysis of electronic spectra of CoCl4^2 ion

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