Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (3): 222-226.     Next Articles

Original Articles

单分子分解成两个自由基反应的半经典统计方法I. 关于CH4分解成CH3.和H.自由基的研究

丁世良;邓从豪;王泽新   

  1. 山东大学理论化学研究室;青岛化工学院化工系
  • 发布日期:1990-03-15

Method of the semiclassical statistics for unimolecular reactions to form two radicals I. decomposition of CH4 to CH3. and H.

DIN SHILIAN;DENG CONGHAO;WANG ZEXIN   

  • Published:1990-03-15

In the temperature range of 300-1500 K, the average values of the crit. bond lengths of transition states, the frequency factors, the activation energies, and the rate constants for the chem. reaction CH4 ?CH3. + H. was studied.

Key words: METHYL GROUP, HYDROGEN, METHANE, FREE RADICAL REACTION, ACTIVATION ENERGY, DECOMPOSITION REACTION, REACTION RATE CONSTANT, SEMICLASSICAL CALCULATION, UNIMOLECULAR REACTION

CLC Number: