Acta Chimica Sinica ›› 2023, Vol. 81 ›› Issue (8): 1081-1100.DOI: 10.6023/A23040126 Previous Articles    



崔国庆*(), 胡溢玚, 娄颖洁, 周明霞, 李宇明, 王雅君, 姜桂元, 徐春明*()   

  1. 中国石油大学(北京) 重质油全国重点实验室 北京 102249
  • 投稿日期:2023-04-10 发布日期:2023-09-14
  • 作者简介:

    崔国庆, 博士, 硕士生导师, 2020年6月在北京化工大学获得化学工程与技术博士学位, 师从段雪教授和卫敏教授. 2020年至今在中国石油大学(北京)重质油全国重点实验室从事能源催化方面的研究工作, 目前, 已在Nat. Commun.、Angew. Chem. Int. Ed.、ACS Catal.、Appl. Catal. B: Environ.、J. Catal.和《化工学报》等期刊发表研究论文20余篇, 获2021年中国分析测试协会科学技术奖(CAIA奖)一等奖1项等.

    胡溢玚, 中国石油大学(北京)在读研究生, 2021年6月于中国石油大学(北京)化学工程与环境学院获得能源化学工程学士学位, 主要研究方向为二氧化碳的热催化转化与高效利用.

    徐春明, 教授, 博士生导师, 中国科学院院士, 重质油全国重点实验室主任, 碳中和未来技术学院院长, 山东石油化工学院院长, 国家杰出青年基金获得者, “全国优秀教师”称号获得者, 国家“万人计划”百千万工程领军人才, 国家自然科学基金创新研究群体项目负责人, 全国优秀教师, 北京市教学名师, 北京市课程思政教学名师, 国家级教学团队负责人, 中国化工学会副理事长. 主要致力于重油高效转化和清洁油品生产、新能源技术等研究, 主持国家重点研发、国家基金委创新研究群体、重点基金等20余个项目, 获国家技术发明二等奖1项, 国家科技进步二等奖2项, 中国石油和化学工业联合会技术发明特等奖1项, 省部级一等奖8项等, 发表高水平论文300余篇, 撰写专著4部, 授权国际发明专利36件、中国发明专利102件, 其中实施转化48件等.

  • 基金资助:
    项目受国家自然科学基金(22109177); 中央高校基本科研业务费专项资金(2462020BJRC008)

Research Progress on the Design, Preparation and Properties of Catalysts for CO2 Hydrogenation to Alcohols

Guoqing Cui(), Yiyang Hu, Yingjie Lou, Mingxia Zhou, Yuming Li, Yajun Wang, Guiyuan Jiang, Chunming Xu()   

  1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing 102249
  • Received:2023-04-10 Published:2023-09-14
  • Contact: *E-mail:;
  • About author:
    † These authors contributed equally to this work.
  • Supported by:
    National Natural Science Foundation of China(22109177); Fundamental Research Funds for the Central Universities(2462020BJRC008)

CO2, as one of the most important renewable C1 resource and oxygen resource, has the advantages of abundant reserves, low price, safe and non-toxic, etc. CO2 can be converted into high-value chemicals and fuels such as alcohols with the help of the heterogeneous thermal-catalytic technologies, which have attracted widespread attention and developed rapidly in both academic research and industrial applications. In particular, the design and preparation of the catalysts with satisfactory catalytic CO2 hydrogenation performance (high activity, selectivity and stability) at mild condition still remain a huge challenge. In recent years, the structural design of catalysts for CO2 hydrogenation to alcohols has been widely reported, in which great advances have been achieved in the metal-based and metal oxide-based catalysts. In this review, the basic reaction steps and reaction mechanism for the hydrogenation reaction of carbon dioxide to methanol, ethanol and other C2+ alcohols are overviewed in details. The structural characteristic, catalytic performance and structure-activity relationship are analyzed and categorized from the perspective of metals, metal oxide, metal carbide and metal sulfide components. Finally, the challenges and potential research directions of CO2 hydrogenation to alcohols are elucidated and prospected in the future.

Key words: CO2 hydrogenation, alcohols, catalyst, structure design, reaction mechanism