Crystal and Electronic Structure of Novel Organic-Inorganic Hybrid Coordination Polymer {[C12H28N2][(Pb3I8) (DMF)2]•2DMF}n

Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (8): 697-702. Previous Articles Next Articles

Original Articles

有机-无机杂化配位聚合物{[C₁₂H₂₈N₂][(Pb₃I₈) (DMF)₂]•2DMF}_n的晶体及电子结构

李浩宏¹，陈之荣*¹，李俊篯¹，黄长沧¹，肖光参²，连照勋¹，胡晓琳¹

(¹福州大学化学化工学院福州 350002)
(²福州大学测试中心福州 350002)

投稿日期:2004-06-14 修回日期:2004-12-24 发布日期:2010-12-10
通讯作者: 陈之荣

Crystal and Electronic Structure of Novel Organic-Inorganic Hybrid Coordination Polymer {[C₁₂H₂₈N₂][(Pb₃I₈) (DMF)₂]•2DMF}_n

LI Hao-Hong¹, CHEN Zhi-Rong*¹, LI Jun-Qian¹, HUANG Chang-Cang¹, XIAO Guang-Can², LIAN Zhao-Xun¹, HU Xiao-Lin¹

(¹College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002)
(²Center of Analysis and Measurement, Fuzhou University, Fuzhou 350002)

Received:2004-06-14 Revised:2004-12-24 Published:2010-12-10
Contact: CHEN Zhi-Rong

Abstract

A novel organic-inorganic hybrid coordination polymer {[C₁₂H₂₈N₂] [(Pb₃I₈) (DMF)₂]•2DMF}_n was synthesized by self-assembling method and characterized by IR, UV/Vis and thermal analysis. The crystal structure was determined by X-ray diffraction analysis and its quantum chemical calculation was performed by Gaussian03 program. The title compound consists of cations ([C₁₂H₂₈N₂]^2＋) and anion chains ([(Pb₃I₈)(DMF)₂^2－]_n) that are combined by static attractive forces in the crystal.

Key words: organic-inorganic hybrid, crystal structure, coordination polymer

Cite this article

LI Hao-Hong, CHEN Zhi-Rong*, LI Jun-Qian, HUANG Chang-Cang, XIAO Guang-Can², LIAN Zhao-Xun, HU Xiao-Lin. Crystal and Electronic Structure of Novel Organic-Inorganic Hybrid Coordination Polymer {[C₁₂H₂₈N₂][(Pb₃I₈) (DMF)₂]•2DMF}_n[J]. Acta Chimica Sinica, 2005, 63(8): 697-702.

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有机-无机杂化配位聚合物{[C₁₂H₂₈N₂][(Pb₃I₈) (DMF)₂]•2DMF}_n的晶体及电子结构

Crystal and Electronic Structure of Novel Organic-Inorganic Hybrid Coordination Polymer {[C₁₂H₂₈N₂][(Pb₃I₈) (DMF)₂]•2DMF}_n

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有机-无机杂化配位聚合物{[C12H28N2][(Pb3I8) (DMF)2]•2DMF}n的晶体及电子结构