Studies on reaction of iron carbonyl-mercaptan-triethylamine system: synthesis of  μ-acyl or μ-alkenyl Fe-S complexes and kinetics for CO extrusion reaction

Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (2): 110-115. Previous Articles Next Articles

Original Articles

羰基铁-硫醇-三乙胺反应体系的研究, μ-酰基与μ-烯基铁硫配合物的合成系脱羰反应动力学

宋礼成;刘全亭;王积涛

南开大学化学系

发布日期:1990-02-15

Studies on reaction of iron carbonyl-mercaptan-triethylamine system: synthesis of μ-acyl or μ-alkenyl Fe-S complexes and kinetics for CO extrusion reaction

SONG LICHENG;LIU QUANTING;WANG JITAO

Published:1990-02-15

Abstract

Two new m-acyl Fe-S complexes (m-R1S)(m-CH3CH:CHCO)Fe2(CO)6 (R1 = Et, tert-Bu) and three new m-alkenyl complexes (m-R1S)(m-CH3CH:CH)Fe2(CO)6 (R1 = Et, tert-Bu, CH2:CHCH2) have been synthesized by reactions of trans-crotonyl chloride with active intermediates [(m-CO)(m-R1S)Fe2(CO)6]- Et3N+H. The kinetics of CO extrusion reaction of m-acyl complexes to form m-alkenyl complexes has been investigated and showed that this type of reaction is first-order. The rate constants and half-life of the reactants have been calculated

Key words: MERCAPTAN, REACTION KINETICS, ALKENE, IRON COMPLEX, IRON COMPLEX, HALF LIFE, CARBONYL COMPOUNDS, REACTION RATE CONSTANT, SULFIDE COMPLEX, ACYL GROUP

CLC Number:

O641
O643

Cite this article

SONG LICHENG;LIU QUANTING;WANG JITAO. Studies on reaction of iron carbonyl-mercaptan-triethylamine system: synthesis of μ-acyl or μ-alkenyl Fe-S complexes and kinetics for CO extrusion reaction[J]. Acta Chimica Sinica, 1990, 48(2): 110-115.

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羰基铁-硫醇-三乙胺反应体系的研究, μ-酰基与μ-烯基铁硫配合物的合成系脱羰反应动力学

Studies on reaction of iron carbonyl-mercaptan-triethylamine system: synthesis of μ-acyl or μ-alkenyl Fe-S complexes and kinetics for CO extrusion reaction

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