Synthesis of homoallyl alcohol from carbonyl compounds by allyl halide and tin

Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (4): 372-376. Previous Articles Next Articles

Original Articles

烯丙基卤和锡与醛, 酮反应合成高烯丙基醇

吴世晖;黄邦洲;朱天民;姚丹姝;初永亮

复旦大学化学系

发布日期:1990-04-15

Synthesis of homoallyl alcohol from carbonyl compounds by allyl halide and tin

WU SHIHUI;HUANG BANGZOU;ZHU TIANMIN;YAO DANSHU;CHU YONGLIANG

Published:1990-04-15

Abstract

Homoallyl alcs. containing hydroxy, phenolic hydroxyl, aromatic nitro and bromo groups can be obtained directly from the reaction of corresponding carbonyl compounds with allyl halide and tin powder in good yields. The effect of solvents and the amount of water present on product yields were discussed.

Key words: IODINE COMPOUNDS, BROMINE COMPOUNDS, TIN, ALCOHOL, CARBONYL COMPOUNDS, ALDEHYDES, KETONE, ALLYL GROUP, ALLYL GROUP, ORGANIC REAGENTS

CLC Number:

O621

Cite this article

WU SHIHUI;HUANG BANGZOU;ZHU TIANMIN;YAO DANSHU;CHU YONGLIANG. Synthesis of homoallyl alcohol from carbonyl compounds by allyl halide and tin[J]. Acta Chimica Sinica, 1990, 48(4): 372-376.

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烯丙基卤和锡与醛, 酮反应合成高烯丙基醇

Synthesis of homoallyl alcohol from carbonyl compounds by allyl halide and tin

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