Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (5): 512-515. Previous Articles     Next Articles

Original Articles

苷类化合物研究 IV: 熊果苷类似物的合成

彭师奇;李立;吴建伟;安谊;程铁明;蔡孟深   

  1. 北京医科大学药学院
  • 发布日期:1989-05-15

Studies on glycosides IV: Synthesis of arbutin analogs

PENG SHIQI;LI LI;WU JIANWEI;AN YI;CHENG TIEMING;CAI MENGSHEN   

  • Published:1989-05-15

Arbutin analogs were synthesized by reacting 1-bromo-2,3,4,6-tetra-O-acetyl-a-D-glucopyranose or galactopyranose with dihydroxybenzenes followed by mild hydrolysis with methanolic ammonia. The anomeric configurations of these glycosides were assigned based on 1H NMR and comparison of 1-C chem. shifts on the sugar moieties.

Key words: BROMINE COMPOUNDS, PYRANOSE, GLUCOSE, ANALOGUE, GLYCOSIDE, ACETYL GROUP, BENZENEDIOL, ARBUTIN

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