Transitional-metal carbene complexes VI: Synthesis and spectrum of iron-sulfur cluster carbene complexes of mono-,dimanganese and dirhenium-C5H5(CO)2MnC(C6H5)(μ-S)(μ-C6H5S)Fe2 (CO)6 and [π-C5H5(CO)2MC(C6H5)]2(μ-S)2-Fe2(CO)6(M=Mn, Re)

Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (1): 31-36. Previous Articles Next Articles

Original Articles

过渡金属卡宾配合物 VI:单、双核锰和双核铼的铁硫原子簇卡宾配合物-π-C5H5(CO)2MnC(C6H5)(μ-S)(μ-C6H5S)Fe2(CO)6和[π-C5H5(CO)2MC(C6H5)]2(μ-S)2Fe2(CO)6(M=Mn,Re)的合成和波谱

陈家碧;雷杜馨;张泽莹;唐有祺

中国科学院上海有机化学研究所;北京大学物理化学研究所

发布日期:1989-01-15

Transitional-metal carbene complexes VI: Synthesis and spectrum of iron-sulfur cluster carbene complexes of mono-,dimanganese and dirhenium-C5H5(CO)2MnC(C6H5)(μ-S)(μ-C6H5S)Fe2 (CO)6 and [π-C5H5(CO)2MC(C6H5)]2(μ-S)2-Fe2(CO)6(M=Mn, Re)

CHEN JIABI;LEI DUXIN;ZHANG ZEYING;TANG YOUQI

Published:1989-01-15

Abstract

Reaction of p-cyclopentadienyl(dicarbonyl)(phenylcarbyne) manganese tetrabromoborate, [p-C5H5(CO)2MnCC6H5]BBr4 (I), with an equimolar quantity of (m-phenylthio)(m-thiolato)hexacarbonyldiiron anion affords p-cyclopentadienyl(dicarbonyl){phenyl[(phenylthio)hexacarbonyldiiron(m-t hio)]carbene}manganese (II), the crystal structure of which was determine Two molar quantities of I or p-cyclopentadienyl(dicarbonyl)(phenylcarbyne)rhenium tetrabromoborate, [p-C5H5(CO)2ReCC6H5]BBr4, reacts with one molar quantity of bis(m-thiolato)hexacarbonyldiiron dianion to give [hexacarbonylbis(m-thio)carbene] manganese and -rhenium, [p-C5H5(CO)2MnC(C6H5)]2(m-S)2Fe2(CO)6 and [p-C5H5(CO)2ReC(C6H5)]2(m-S)2Fe2(CO)6, resp.

Key words: INFRARED SPECTROPHOTOMETRY, X-RAY DIFFRACTION ANALYSIS, MASS SPECTROGRAPHY, CYCLOPENTADIENE P, IRON COMPLEX, CARBONYL COMPLEX, CARBENE, PROTON MAGNETIC RESONANCE SPECTROMETRY, STRUCTURAL ANALYSIS, CLUSTER COMPOUND

CLC Number:

O627

Cite this article

CHEN JIABI;LEI DUXIN;ZHANG ZEYING;TANG YOUQI. Transitional-metal carbene complexes VI: Synthesis and spectrum of iron-sulfur cluster carbene complexes of mono-,dimanganese and dirhenium-C5H5(CO)2MnC(C6H5)(μ-S)(μ-C6H5S)Fe2 (CO)6 and [π-C5H5(CO)2MC(C6H5)]2(μ-S)2-Fe2(CO)6(M=Mn, Re)[J]. Acta Chimica Sinica, 1989, 47(1): 31-36.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Jian Zheng, Jin-Hong Lin, Ji-Chang Xiao. Difluorocarbene-based Trifluoromethylthiolation of Aryl and Alkenyl Iodides [J]. Acta Chimica Sinica, 2024, 82(2): 115-118.
[2]	Lefei Yu, Xing-Qi Yao, Jianbo Wang. Recent Advance of Diazo Compounds in Polymer Synthesis^★ [J]. Acta Chimica Sinica, 2023, 81(8): 1015-1029.
[3]	Yanyan Ren, Xin Li, Yingfeng Han. Synthesis and Optical Property Studies of Blue-Light Organic Radicals Based on N-Heterocyclic Carbenes^★ [J]. Acta Chimica Sinica, 2023, 81(7): 735-740.
[4]	Qingduan Meng, Jiahong Han, Yixiao Pan, Wei Hao, Qing-Hua Fan. Asymmetric Synthesis of C₁-Symmetric Chiral N-Heterocyclic Carbene (NHC) Ligands and Their Applications in Asymmetric Catalysis^★ [J]. Acta Chimica Sinica, 2023, 81(10): 1271-1279.
[5]	Shangzhao Li, Zhenwu Ouyang, Junjie Zou, Dongyang Wang, Bin Xu, Liang Deng. A Mononuclear Iron Thiolate Complex with N-Heterocyclic Carbene Ligation [J]. Acta Chimica Sinica, 2022, 80(3): 272-276.
[6]	Jiang Liu, Jingcheng Xu, Romana Pajkert, Haibo Mei, Gerd-Volker Röschenthaler, Jianlin Han. Esterification of Carboxylic Acids with (β-Diazo-α,α-difluoroethyl)phosphonates under Photochemical Conditions [J]. Acta Chimica Sinica, 2021, 79(6): 747-750.
[7]	Fan Yiming, Cheng Jun, Gao Yafei, Shi Min, Deng Liang. Iron Dinitrogen Complexes Supported by Tris(NHC)borate Ligand: Synthesis, Characterization, and Reactivity Study [J]. Acta Chim. Sinica, 2018, 76(6): 445-452.
[8]	Ma Xingxing, Xuan Qingqing, Song Qiuling. N—H and O—H Difluoromethylation of N-Heterocycles [J]. Acta Chim. Sinica, 2018, 76(12): 972-976.
[9]	Lu Hong, Liu Jin-Yu, Li Hong-Yu, Xu Peng-Fei. Recent Developments in N-Heterocyclic Carbene and Transition-Metal Cooperative Catalysis [J]. Acta Chim. Sinica, 2018, 76(11): 831-837.
[10]	Li Maolin, Chen Mengqing, Xu Bin, Zhu Shoufei, Zhou Qilin. Enantioselective O-H Bond Insertion of α-Diazoketones with Alcohols Cooperatively Catalyzed by Achiral Dirhodium Complexes and Chiral Spiro Phosphoric Acids [J]. Acta Chim. Sinica, 2018, 76(11): 883-889.
[11]	Wang Leming, Wang Qian, Chen Jiean, Huang Yong. Switching Reaction Pathways by Cooperative Catalysis of N-Heterocyclic Carbene and Lewis Acids [J]. Acta Chim. Sinica, 2018, 76(11): 850-856.
[12]	Li Xin-Ling, Wang Jia-Qi, Li Long, Yin Ying-Wu, Ye Long-Wu. Facile Synthesis of 2H-Pyrroles: Combination of Gold Catalysis and Lewis Acid Catalysis [J]. Acta Chim. Sinica, 2016, 74(1): 49-53.
[13]	Cheng Qingqing, Xu Huan, Zhu Shoufei, Zhou Qilin. Enantioselective Copper-Catalyzed B—H Bond Insertion Reaction of α-Diazoketones [J]. Acta Chim. Sinica, 2015, 73(4): 326-329.
[14]	Sun Lihui, Liang Zhiqin, Ye Song. Asymmetric N-Heterocyclic Carbene-catalyzed [4+2] Cycloaddition of Ketenes with α-cyanochalcones [J]. Acta Chimica Sinica, 2014, 72(7): 841-844.
[15]	Zhang Chunhong, Zhang Hong, Wei Ailin, He Xumin, Xia Haiping. Synthesis of Ruthena-polycyclic Complexes by Ruthenium-Vinylcarbene Complex [J]. Acta Chimica Sinica, 2013, 71(10): 1373-1378.

过渡金属卡宾配合物 VI:单、双核锰和双核铼的铁硫原子簇卡宾配合物-π-C5H5(CO)2MnC(C6H5)(μ-S)(μ-C6H5S)Fe2(CO)6和[π-C5H5(CO)2MC(C6H5)]2(μ-S)2Fe2(CO)6(M=Mn,Re)的合成和波谱

Transitional-metal carbene complexes VI: Synthesis and spectrum of iron-sulfur cluster carbene complexes of mono-,dimanganese and dirhenium-C5H5(CO)2MnC(C6H5)(μ-S)(μ-C6H5S)Fe2 (CO)6 and [π-C5H5(CO)2MC(C6H5)]2(μ-S)2-Fe2(CO)6(M=Mn, Re)

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments