Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (6): 612-614. Previous Articles     Next Articles

Original Articles

活性镁及活性氢化镁的合成

廖世健;张双青;余淑文   

  1. 中国科学院大连化学物理研究所
  • 发布日期:1988-06-15

Synthesis of active magnesium and magnesium hydride

LIAO SHIJIAN;ZHANG SHUANGQING;YU SHUWEN   

  • Published:1988-06-15

MgH2 was prepared at normal pressure simply by decomposing Mg anthracene thermally under vacuum and then hydrogenating the resulting activated Mg. In this process, Mg is activated while anthracene can be recycled in principle without consuming any reagent. The hydrogenation behavior of the activated Mg can be modified by doping the Mg anthracene with transition metal compounds before decomposition The doped Mg can take up H even at 90?

Key words: MAGNESIUM, REACTION KINETICS, HYDROGENATION, CYCLOPENTADIENE P, ACTIVATION, DOPE, HYDRIDES, TITANIUM COMPLEX, MAGNESIUM COMPOUNDS, ORGANO TRANSITION METAL COMPLEX

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