Studies on adiabatic thermokinetics II: Thermokinetic research of first-order reactions

Abstract

On the basis of the thermokinetic transform equations proposed by one of the authors (Y. Dent, 1985), an adiabatic thermokinetic study of two first-order reaction systems, the alkaline hydrolysis of benzoic ester in aqueous alcohol and of benzyl chloride in aqueous DMSO, has been undertaken. The calculated rate constants of these two reactions agree with the values in the literature. A linear correction method for external heat effects is suggested.

Key words: RATE, REACTION KINETICS, HYDROLYSIS, MATHEMATICAL MODELS, THERMODYNAMICS, ETHYL ESTER, BENZENECARBOXYLIC ACID P, DMSO, KINETICS EQUATIONS, CALORIMETRY

CLC Number:

O643

Cite this article

YANG MINGLI;ZHAN SHUGUANG;DENG YU. Studies on adiabatic thermokinetics II: Thermokinetic research of first-order reactions[J]. Acta Chimica Sinica, 1987, 45(2): 127-132.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Cheng-Qiang Wang, Chao Feng. Applications of Nucleophilic Fluorine Sources in the Selective Fluorofunctionalization of Unsaturated Carbon-Carbon Bonds [J]. Acta Chimica Sinica, 2024, 82(2): 160-170.
[2]	Yujie Yang, Yuxiu Gong, Tianhang Gu, Wei-xian Zhang. Progress and Environmental Research Applications of Cryo-Electron Microscopy^★ [J]. Acta Chimica Sinica, 2023, 81(8): 990-1001.
[3]	Jie Yang, Lin Ling, Yuxue Li, Long Lu. Density Functional Theory Study on Thermal Decomposition Mechanisms of Ammonium Perchlorate [J]. Acta Chimica Sinica, 2023, 81(4): 328-337.
[4]	Han Zha, Jin Fang, Lingpeng Yan, Yongzhen Yang, Changqi Ma. Research Progress of Thermal Failure Mechanism and Ternary Blending to Improve Thermal Stability of Organic Solar Cells [J]. Acta Chimica Sinica, 2023, 81(2): 131-145.
[5]	Juan Wang, Huamin Xiao, Ding Xie, Yuanru Guo, Qingjiang Pan. Density Functional Theory Study of Structures of Copper-doped and Graphitic Carbon Nitride-combined Zinc Oxides and Their Boosted Nitrogen Dioxide-sensing Performance [J]. Acta Chimica Sinica, 2023, 81(11): 1493-1499.
[6]	Xiawei Ying, Jianjun Fu, Min Zeng, Wen Liu, Tianyu Zhang, Peikang Shen, Xinyi Zhang. BiOCl-Fe₂O₃@TiO₂ Mesoporous Composite for Photoelectrochemical Synthesis of Ammonia [J]. Acta Chimica Sinica, 2022, 80(4): 503-509.
[7]	Haikuo Gao, Zhagen Miao, Wenping Hu, Huanli Dong. Research on Key Materials and Devices of Organic Light-emitting Transistors^※ [J]. Acta Chimica Sinica, 2022, 80(3): 327-339.
[8]	Qing Huang, Rui Ding, Lai Chen, Yun Lu, Qi Shi, Qiyu Zhang, Qijun Nie, Yuefeng Su, Feng Wu. Dual-Decoration and Mechanism Analysis of Ni-rich LiNi_0.83Co_0.11Mn_0.06O₂ Cathodes by Na₂PO₃F [J]. Acta Chimica Sinica, 2022, 80(2): 150-158.
[9]	Yinghui Wang, Simin Wei, Jinwei Duan, Kang Wang. Mechanism of Silyl Enol Ethers Hydrogenation Catalysed by Frustrated Lewis Pairs: A Theoretical Study [J]. Acta Chimica Sinica, 2021, 79(9): 1164-1172.
[10]	Junyao Xie, Xiaoming Zeng, Meiming Luo. Ni-Catalysed Regioselective α,β-Diarylation of α,β-Unsaturated Aldehydes [J]. Acta Chimica Sinica, 2021, 79(9): 1118-1122.
[11]	Anqi Zhang, Qilu Yao, Zhang-Hui Lu. Recent Progress on Catalysts for Hydrogen Evolution from Decomposition of Hydrous Hydrazine [J]. Acta Chimica Sinica, 2021, 79(7): 885-902.
[12]	Runzhou Gao, Guochang Li, Yiqun Chen, Yu Zeng, Jie Zhao, Qiang Wu, Lijun Yang, Xizhang Wang, Zheng Hu. Carbon Nanocages//Tungsten Trioxide Nanorods Supercapacitors with in situ Polymerized Gel Electrolytes [J]. Acta Chimica Sinica, 2021, 79(6): 755-762.
[13]	Xue Dong, Hong Cao, Lei Xu, Zhipeng Wang, Jing Chen, Chao Xu. Advances in Environmental Coordination Chemistry of Np and Pu with Inorganic Anions in Aqueous Solution [J]. Acta Chimica Sinica, 2021, 79(12): 1415-1424.
[14]	Min Zhao, Xue Wang, Yanan Liu, Yufei He, Dianqing Li. Preparation of Efficient Pd/MgAl-LDO@Al₂O₃ Catalyst for Phenol Hydrogenation to Cyclohexanone [J]. Acta Chimica Sinica, 2021, 79(12): 1518-1525.
[15]	Tang Gong-ao, Mao Kun, Zhang Jing, Lyu Pin, Cheng Xueyi, Wu Qiang, Yang Lijun, Wang Xizhang, Hu Zheng. Hierarchical Nitrogen-doped Carbon Nanocages as High-rate Long-life Cathode Material for Rechargeable Magnesium Batteries [J]. Acta Chimica Sinica, 2020, 78(5): 444-450.

绝热式热动力学的研究II: 一级反应的热谱解析