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Acta Chimica Sinica ›› 1998, Vol. 56 ›› Issue (8): 819-826. Previous Articles Next Articles
Original Articles
陈建新;潘继刚;夏炽中;程津培
发布日期:
CHEN JIANXIN;PAN JIGANG;XIA CHIZHONG;CHENG JINPEI
Published:
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Substituted imidazolinium salt, 1, 2-dimethyl-3-(p-methoxybenzenesulfonyl)-imidazolinium iodide, as a tetrahydrofolate model in terms of the ability to transfer a substituted one-carbon unit (ethylidyne, nitromethylethylidene) at the level of formate or formaldehyde, has been synthesized by mimicking the structure and property of tetrahydrofolate coenzyme. The model compound can react with a variety of mono- and bifunctional nucleophiles and lead to some carboline alkaloids and other heterocyclic compounds.
Key words: IMIDAZOLE P, IODINE COMPOUNDS, ORGANIC SYNTHESIS, BIONICS, TETRAHYDRO-COMPOUNDS, C1 COMPOUNDS, FOLIC ACID, TRANSFER REACTIONS, COENZYME, NUCLEOPHILIC REAGENTS
CLC Number:
Q55
CHEN JIANXIN;PAN JIGANG;XIA CHIZHONG;CHENG JINPEI. Mimicking of structure and properties of tetrahydrofolic coenzyme and study on their substituted one-carbon unit transfer reactions[J]. Acta Chimica Sinica, 1998, 56(8): 819-826.
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