Linear free energy relationships in coordination chemistry XXII. Cu(II)-α-aminoacids-dioxotetraamine macrocycles

Acta Chimica Sinica ›› 1997, Vol. 55 ›› Issue (10): 991-997. Previous Articles Next Articles

Original Articles

配位化学中的直线自由能关系XXII: 铜(II)-α-氨基酸-二氧四胺大环三元体系

林华宽;朱守荣;APPOLIN, B. KONDIANO;寇福平;陈荣悌

南开大学化学系

发布日期:1997-10-15

Linear free energy relationships in coordination chemistry XXII. Cu(II)-α-aminoacids-dioxotetraamine macrocycles

LIN HUAKUAN;ZHU SHOURONG;APPOLIN, B. KONDIANO;KOU FUPING;CHEN RONGTI

Published:1997-10-15

Abstract

The stability of Cu(II)-α -aminoacids-13-(2'-hydroxy-3', 5'-substituted benzyl)-1, 4, 8, 11-tetraazacyclotetradecane-12, 14-dione (RTADO-14) ternary complex compounds has been studied by means of pH titration method at 25.0±0.1℃ and I=0.1 mol.dm^-^3 KNO3. The formation constants of ternary complex compounds were obtained. The structures of ternary complex compounds and the effect of substituents on macrocyclic ligands were also discussed.

Key words: AMINO ACID, STABILITY, COPPER COMPLEX, FREE ENERGY

CLC Number:

O611.662

Cite this article

LIN HUAKUAN;ZHU SHOURONG;APPOLIN, B. KONDIANO;KOU FUPING;CHEN RONGTI. Linear free energy relationships in coordination chemistry XXII. Cu(II)-α-aminoacids-dioxotetraamine macrocycles[J]. Acta Chimica Sinica, 1997, 55(10): 991-997.

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配位化学中的直线自由能关系XXII: 铜(II)-α-氨基酸-二氧四胺大环三元体系

Linear free energy relationships in coordination chemistry XXII. Cu(II)-α-aminoacids-dioxotetraamine macrocycles

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